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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Structure
  • ₹4100 - ₹192587
  • Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • CAS: 35138-22-8
  • MF: C16H24BF4Rh
  • MW: 406.07
  • EINECS:460-220-1
  • MDL Number:MFCD00075045
  • Synonyms:Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX;Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
Price5 Properties Safety Information Description
5 prices
Selected condition：

Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 1g
  • 5g
  • ManufacturerALFA India
  • Product numberALF-044031-06
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging5g
  • Price₹32577
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-044031-03
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging1g
  • Price₹192587
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB3961
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
  • Packaging100MG
  • Price₹4100
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB3961
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
  • Packaging1G
  • Price₹19600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number14694
  • Product descriptionBis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging100MG
  • Price₹13286.7
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-044031-06 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 5g ₹32577 2022-05-26 Buy
ALFA India ALF-044031-03 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1g ₹192587 2022-05-26 Buy
TCI Chemicals (India) B3961 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 100MG ₹4100 2022-05-26 Buy
TCI Chemicals (India) B3961 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 1G ₹19600 2022-05-26 Buy
Sigma-Aldrich(India) 14694 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 100MG ₹13286.7 2022-06-14 Buy

Properties

Melting point :210 °C
Density :0.42 g/cm3 (20℃)
storage temp. :Inert atmosphere,Store in freezer, under -20°C
solubility :Chloroform (Slightly), Methanol (Slightly)
form :Powder
color :Red
PH :7 (5g/l, H2O, 20℃)
Water Solubility :insoluble
Sensitive :Slightly air & moisture sensitive
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 InChIKey :IEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference :35138-22-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2		 Danger
Warning		 GHS hazard pictograms P210, P240,P241, P280, P370+P378
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

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Suppliers and manufacturers

Evans Fine Chem SOLFYN INTERNATIONAL LLP Omkar Lab Johnson Matthey Chemicals India Pvt Ltd Synthesis With Catalysts Pvt. Ltd. Synthesis With Catalysts Private Limited A.J Chemicals Clearsynth Labs Johnson Matthey Chemicals India Pvt., Ltd. TCI Chemicals (India) Pvt. Ltd.