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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organozirconium >Bis(cyclopentadienyl)dimethylzirconium

Bis(cyclopentadienyl)dimethylzirconium

Bis(cyclopentadienyl)dimethylzirconium Structure
  • ₹7274.4
  • Product name: Bis(cyclopentadienyl)dimethylzirconium
  • CAS: 12636-72-5
  • MF: C12H16Zr
  • MW: 251.48
  • EINECS:
  • MDL Number:MFCD01073786
  • Synonyms:ZIRCONOCENE DIMETHYL;BIS(CYCLOPENTADIENYL)DIMETHYLZIRCONIUM;BIS(CYCLOPENTADIENYL)DIMETHYLZIRCONIUM(IV);BIS(CYCLOPENTADIENYL)ZIRCONIUM DIMETHYL;DIMETHYLZIRCONOCENE;Dimethylcirconocene;Dimethylbis(cyclopentadienyl)zirconium, ;Bis(cyclopentadienyl)dimethylzirconium,min.97%
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Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number483656
  • Product descriptionBis(cyclopentadienyl)dimethylzirconium(IV) 97%
  • Packaging1G
  • Price₹7274.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 483656 Bis(cyclopentadienyl)dimethylzirconium(IV) 97% 1G ₹7274.4 2022-06-14 Buy

Properties

Melting point :170 °C (dec.)(lit.)
Boiling point :170°C
storage temp. :below 5° C
form :crystal
color :white
Sensitive :Air Sensitive
CAS DataBase Reference :12636-72-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Catalyst for:
  • Cationic ring-opening polymerization reactions
  • Markovnikov-selective intermolecular hydrothiolation of terminal alkynes
  • Ziegler-Natta polymerizations of alkenes
  • Methylalumination of heterosubstituted arylethynes

  • Precatalyst for intramolecular hydroamination/cyclisation of aminoallenes

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