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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organonickel >BIS(1,5-CYCLOOCTADIENE)NICKEL(0)

BIS(1,5-CYCLOOCTADIENE)NICKEL(0)

BIS(1,5-CYCLOOCTADIENE)NICKEL(0) Structure
  • ₹7800 - ₹36300
  • Product name: BIS(1,5-CYCLOOCTADIENE)NICKEL(0)
  • CAS: 1295-35-8
  • MF: C16H24Ni
  • MW: 275.06
  • EINECS:215-072-0
  • MDL Number:MFCD00058902
  • Synonyms:Bis(1,5-cyclooctadiene)nickel(O), 98+%;Bis(1,5-cyclooctadiene)nickel(0) 1GR;Bis(1,5-cyclooctadiene)nickel(0) 5GR;Bis(1,5-cyclooctadiene)nickel (0),98% Ni(COD)2;bis(1,5-cyclooctadiene)-nicke ;Bis-1,5-cyclooctadienylnickel;Di(1,5-cyclooctadiene)nickel;Dicyclooctadiene nickel
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 2G
  • 5G
  • 5EACH
  • ManufacturerTCI Chemicals (India)
  • Product numberB5417
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0) (Wax encapsulated) (ca. 0.05mmol/capsule)
  • Packaging5EACH
  • Price₹7800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB3095
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging5G
  • Price₹36300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number244988
  • Product descriptionBis(1,5-cyclooctadiene)nickel(0)
  • Packaging2G
  • Price₹8194.53
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B5417 Bis(1,5-cyclooctadiene)nickel(0) (Wax encapsulated) (ca. 0.05mmol/capsule) 5EACH ₹7800 2022-05-26 Buy
TCI Chemicals (India) B3095 Bis(1,5-cyclooctadiene)nickel(0) 5G ₹36300 2022-05-26 Buy
Sigma-Aldrich(India) 244988 Bis(1,5-cyclooctadiene)nickel(0) 2G ₹8194.53 2022-06-14 Buy

Properties

Melting point :60 °C (dec.)(lit.)
storage temp. :-20°C
solubility :Benzene (Partially Dissolved), THF (Slightly)
form :Shiny Crystalline Powder
color :Gold
Water Solubility :Soluble in benzene, toluene, terahydrofuran, ether, dimethyl formamide, hexamethylphosphoramide, N-methylpyrrolidinone. Insoluble in water.
Sensitive :Air Sensitive
Exposure limits :NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability :Air Sensitive
CAS DataBase Reference :1295-35-8(CAS DataBase Reference)
NIST Chemistry Reference :Nickel, bis[(1,2,5,6-«eta»)-1,5-cyclooctadiene]-(1295-35-8)
EPA Substance Registry System :Bis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]nickel (1295-35-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. It is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

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