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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Silane >Bis(trimethylsilyl)acetylene

Bis(trimethylsilyl)acetylene

Bis(trimethylsilyl)acetylene Structure
  • ₹2800 - ₹74185
  • Product name: Bis(trimethylsilyl)acetylene
  • CAS: 14630-40-1
  • MF: C8H18Si2
  • MW: 170.4
  • EINECS:238-671-9
  • MDL Number:MFCD00008276
  • Synonyms:BIS(TRIMETHYLSILYL)ACETYLENE;Bis(trimethylsilyl)acetylene 99%;TIMTEC-BB SBB008997;1,2-Bis(trimethylsilyl)acetylene;1,2-ethynediylbis[trimethyl-silan ;1,2-ethynediylbis[trimethyl-Silane ;2,5-Disilahex-3-yne, 2,2,5,5-tetramethyl-;Acetylene, bis(trimethylsilyl)-
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 10g
  • 25G
  • 50g
  • 250g
  • ManufacturerALFA India
  • Product numberALF-A11960-09
  • Product descriptionBis(trimethylsilyl)acetylene, 99%
  • Packaging10g
  • Price₹3016
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A11960-18
  • Product descriptionBis(trimethylsilyl)acetylene, 99%
  • Packaging50g
  • Price₹11604
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A11960-30
  • Product descriptionBis(trimethylsilyl)acetylene, 99%
  • Packaging250g
  • Price₹74185
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1090
  • Product descriptionBis(trimethylsilyl)acetylene min. 97.0 %
  • Packaging5G
  • Price₹2800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1090
  • Product descriptionBis(trimethylsilyl)acetylene min. 97.0 %
  • Packaging25G
  • Price₹6900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number187437
  • Product descriptionBis(trimethylsilyl)acetylene 99%
  • Packaging10G
  • Price₹4070.2
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number187437
  • Product descriptionBis(trimethylsilyl)acetylene 99%
  • Packaging50G
  • Price₹15317.38
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-A11960-09 Bis(trimethylsilyl)acetylene, 99% 10g ₹3016 2022-05-26 Buy
ALFA India ALF-A11960-18 Bis(trimethylsilyl)acetylene, 99% 50g ₹11604 2022-05-26 Buy
ALFA India ALF-A11960-30 Bis(trimethylsilyl)acetylene, 99% 250g ₹74185 2022-05-26 Buy
TCI Chemicals (India) B1090 Bis(trimethylsilyl)acetylene min. 97.0 % 5G ₹2800 2022-05-26 Buy
TCI Chemicals (India) B1090 Bis(trimethylsilyl)acetylene min. 97.0 % 25G ₹6900 2022-05-26 Buy
Sigma-Aldrich(India) 187437 Bis(trimethylsilyl)acetylene 99% 10G ₹4070.2 2022-06-14 Buy
Sigma-Aldrich(India) 187437 Bis(trimethylsilyl)acetylene 99% 50G ₹15317.38 2022-06-14 Buy

Properties

Melting point :21-24 °C(lit.)
Boiling point :136-137 °C(lit.)
Density :0.752 g/mL at 25 °C(lit.)
refractive index :n20/D 1.427(lit.)
Flash point :29 °C
storage temp. :2-8°C
solubility :soluble in Chloroform, Methanol
form :liquid
Specific Gravity :0.770
color :colorless
Water Solubility :MAY DECOMPOSE
Hydrolytic Sensitivity :2: reacts with aqueous acid
BRN :906870
InChIKey :ZDWYFWIBTZJGOR-UHFFFAOYSA-N
CAS DataBase Reference :14630-40-1(CAS DataBase Reference)
NIST Chemistry Reference :Silane, 1,2-ethynediylbis[trimethyl-(14630-40-1)
EPA Substance Registry System :Silane, 1,2-ethynediylbis[trimethyl- (14630-40-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

BTMSA is used as starting reagent in the synthesis of functionalized 4-R-1,2-bis(trimethylsilyl)benzenes. It is also used in the synthesis of (+)-brasilenyne2 and (β-diketanato)Ag(BTMSA). Bis(trimethylsilyl)acetylene is a ligand that binds to a central metal ion (e.g. Titanium) to create a coordination complex. One of its complexes, Permethyltitanocene-bis(trimethylsilyl)acetylene, is a catalyst for the head-to-tail dimerization of 1-alkynes (e.g. 3-Penten-1-yne [P227430]).

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