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ChemicalBook > Product Catalogue >Inorganic chemistry >Inorganic salts >Metal halide and Halogen salt >Metal fluoride and salt >NITROSONIUM TETRAFLUOROBORATE

NITROSONIUM TETRAFLUOROBORATE

NITROSONIUM TETRAFLUOROBORATE Structure
  • ₹4270 - ₹21108.75
  • Product name: NITROSONIUM TETRAFLUOROBORATE
  • CAS: 14635-75-7
  • MF: BF4H2NO
  • MW: 118.83
  • EINECS:238-679-2
  • MDL Number:MFCD00011433
  • Synonyms:tetrafluoro-borate(1-nitrosyl ;NITROSONIUM (NITROSYL) TETRAFLUOROBORATE;NITROSONIUM TETRAFLUOROBORATE;nitrosium tetrafluoroborate;Nitrosonium tetrafluoroborate, min. 97%;Nitrosonium tetrafluoroborate,97%;Nitrosoniumtetrafluoroborate,min.97%;Borate(1-), tetrafluoro-, nitrosyl
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Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 5gm
  • 5G
  • 25gm
  • 25G
  • 50gm
  • 50G
  • ManufacturerSigma-Aldrich(India)
  • Product number175064
  • Product descriptionNitrosyl tetrafluoroborate 95%
  • Packaging5G
  • Price₹4270
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number175064
  • Product descriptionNitrosyl tetrafluoroborate 95%
  • Packaging25G
  • Price₹16540.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number175064
  • Product descriptionNitrosyl tetrafluoroborate 95%
  • Packaging50G
  • Price₹21108.75
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number N 2141
  • Product descriptionNitrosyl tetrafluoroborate, 95%
  • Packaging5gm
  • Price₹4608
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number N 2141
  • Product descriptionNitrosyl tetrafluoroborate, 95%
  • Packaging25gm
  • Price₹16506
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number N 2141
  • Product descriptionNitrosyl tetrafluoroborate, 95%
  • Packaging50gm
  • Price₹21006
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 175064 Nitrosyl tetrafluoroborate 95% 5G ₹4270 2022-06-14 Buy
Sigma-Aldrich(India) 175064 Nitrosyl tetrafluoroborate 95% 25G ₹16540.6 2022-06-14 Buy
Sigma-Aldrich(India) 175064 Nitrosyl tetrafluoroborate 95% 50G ₹21108.75 2022-06-14 Buy
ottokemi N 2141 Nitrosyl tetrafluoroborate, 95% 5gm ₹4608 2022-05-26 Buy
ottokemi N 2141 Nitrosyl tetrafluoroborate, 95% 25gm ₹16506 2022-05-26 Buy
ottokemi N 2141 Nitrosyl tetrafluoroborate, 95% 50gm ₹21006 2022-05-26 Buy

Properties

Melting point :250 °C
Boiling point :250°C 0,01mm
Density :2.185
Flash point :250°C/0.01mm subl.
storage temp. :2-8°C
solubility :Soluble in acetonitrile.
form :Crystals or Crystalline Powder
Specific Gravity :2.185
color :White
Sensitive :Hygroscopic
Merck :14,6649
Stability :Hygroscopic, Moisture Sensitive
InChI :InChI=1S/BF4.H2NO/c2-1(3,4)5;1-2/h;1H2/q-1;+1
InChIKey :CYLOZTYJBXHMJA-UHFFFAOYSA-N
SMILES :[NH2+]=O.[B+3]([F-])([F-])([F-])[F-]
CAS DataBase Reference :14635-75-7(CAS DataBase Reference)
EPA Substance Registry System :Borate(1-), tetrafluoro-, nitrosyl (14635-75-7)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

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