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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >Dicarbonylacetylacetonato rhodium(I)

Dicarbonylacetylacetonato rhodium(I)

Dicarbonylacetylacetonato rhodium(I) Structure
  • ₹18603.6 - ₹70707
  • Product name: Dicarbonylacetylacetonato rhodium(I)
  • CAS: 14874-82-9
  • MF: C7H7O4Rh
  • MW: 258.03
  • EINECS:238-947-9
  • MDL Number:MFCD00009884
  • Synonyms:DICARBONYLACETYLACETONATO RHODIUM(I);DICARBONYLRHODIUM(I) 2,4-PENTANEDIONATE;Acetylacetonatorhodium(I) dicarbonyl~Dicarbonyl(2,4-pentanedionato)rhodium(I);Dicarbonyl-(2,4-pentandione)-rhodium ;Dicarbonyl(2,4-pentanedionato)rhodium;Dicarbonylacetylacetonatorhodium;Dicarbonylrhodium acetylacetonate;Rhodium dicarbonylacetylacetonate
4 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 500MG
  • 1gm
  • 1G
  • 2G
  • ManufacturerSigma-Aldrich(India)
  • Product number683183
  • Product descriptionCARAC Umicore, 98%
  • Packaging2G
  • Price₹70707
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number288101
  • Product description(Acetylacetonato)dicarbonylrhodium(I) 98%
  • Packaging1G
  • Price₹37418.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number683183
  • Product descriptionCARAC Umicore, 98%
  • Packaging500MG
  • Price₹18603.6
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number A 1024
  • Product description(Acetylacetonato)dicarbonylrhodium(I) 98%
  • Packaging1gm
  • Price₹39069
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 683183 CARAC Umicore, 98% 2G ₹70707 2022-06-14 Buy
Sigma-Aldrich(India) 288101 (Acetylacetonato)dicarbonylrhodium(I) 98% 1G ₹37418.1 2022-06-14 Buy
Sigma-Aldrich(India) 683183 CARAC Umicore, 98% 500MG ₹18603.6 2022-06-14 Buy
ottokemi A 1024 (Acetylacetonato)dicarbonylrhodium(I) 98% 1gm ₹39069 2022-05-26 Buy

Properties

Melting point :154-156 °C (lit.)
Density :1.96[at 20℃]
vapor pressure :0.13Pa at 25℃
storage temp. :Inert atmosphere,Room Temperature
solubility :Soluble in acetone
form :Needles or Flakes
color :Greenish-red
Water Solubility :insoluble
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 LogP :0.4 at 20℃
NIST Chemistry Reference :Rhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9)
EPA Substance Registry System :Rhodium, dicarbonyl(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (SP-4-2)- (14874-82-9)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.

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