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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >Rhodium(III) 2,4-pentanedionate

Rhodium(III) 2,4-pentanedionate

Rhodium(III) 2,4-pentanedionate Structure
  • ₹9002.1 - ₹243909
  • Product name: Rhodium(III) 2,4-pentanedionate
  • CAS: 14284-92-5
  • MF: C15H21O6Rh
  • MW: 400.23
  • EINECS:238-192-5
  • MDL Number:MFCD00083144
  • Synonyms:4-pentanedionato-o,o’)-tris((oc-6-11)-rhodiu ;Rhodium acetylacetonate;Rhodium tris(acetylacetonate);Rhodium, tris(2,4-pentanedionato)-;Rhodium, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-;Tris(2,4-pentanedionato)rhodium;Tris(acetylacetonato)rhodium;RhodiuM(III) acetylacetonate,98% Rh(CH3COCHCOCH3)3
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Brand

  • Sigma-Aldrich
  • ALFA India
  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 250MG
  • 0.5g
  • 1gm
  • 1G
  • 5gm
  • 5g
  • ManufacturerSigma-Aldrich
  • Product number282774
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging1G
  • Price₹24963.9
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-010561-02
  • Product descriptionRhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min
  • Packaging0.5g
  • Price₹21823
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-010561-03
  • Product descriptionRhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min
  • Packaging1g
  • Price₹43645
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-010561-06
  • Product descriptionRhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min
  • Packaging5g
  • Price₹218226
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number282774
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging250MG
  • Price₹9002.1
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number282774
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging1G
  • Price₹24963.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number282774
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging5G
  • Price₹87934.2
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number R 6791
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging250mg
  • Price₹23904
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number R 6791
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging1gm
  • Price₹79929
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number R 6791
  • Product descriptionRhodium(III) acetylacetonate 97%
  • Packaging5gm
  • Price₹243909
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 282774 Rhodium(III) acetylacetonate 97% 1G ₹24963.9 2022-06-14 Buy
ALFA India ALF-010561-02 Rhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min 0.5g ₹21823 2022-05-26 Buy
ALFA India ALF-010561-03 Rhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min 1g ₹43645 2022-05-26 Buy
ALFA India ALF-010561-06 Rhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min 5g ₹218226 2022-05-26 Buy
Sigma-Aldrich(India) 282774 Rhodium(III) acetylacetonate 97% 250MG ₹9002.1 2022-06-14 Buy
Sigma-Aldrich(India) 282774 Rhodium(III) acetylacetonate 97% 1G ₹24963.9 2022-06-14 Buy
Sigma-Aldrich(India) 282774 Rhodium(III) acetylacetonate 97% 5G ₹87934.2 2022-06-14 Buy
ottokemi R 6791 Rhodium(III) acetylacetonate 97% 250mg ₹23904 2022-05-26 Buy
ottokemi R 6791 Rhodium(III) acetylacetonate 97% 1gm ₹79929 2022-05-26 Buy
ottokemi R 6791 Rhodium(III) acetylacetonate 97% 5gm ₹243909 2022-05-26 Buy

Properties

Melting point :263-264 °C(lit.)
Boiling point :>280°C
storage temp. :Inert atmosphere,Room Temperature
form :Powder
color :Yellow to yellow-orange
Specific Gravity :1.607
Water Solubility :insoluble
Exposure limits :ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 CAS DataBase Reference :14284-92-5
NIST Chemistry Reference :Rhodium, tris(2,4-pentanedionato-o,o')-(14284-92-5)
EPA Substance Registry System :Rhodium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-92-5)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology.

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