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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic hafnium, silver, platinum >HAFNIUM TRIFLUOROMETHANESULFONATE

HAFNIUM TRIFLUOROMETHANESULFONATE

HAFNIUM TRIFLUOROMETHANESULFONATE Structure
  • ₹2000 - ₹35350
  • Product name: HAFNIUM TRIFLUOROMETHANESULFONATE
  • CAS: 161337-67-3
  • MF: CHF3HfO3S
  • MW: 328.56
  • EINECS:
  • MDL Number:MFCD01321255
  • Synonyms:TRIFLUOROMETHANESULFONIC ACID HAFNIUM(4) SALT;TRIFLUOROMETHANESULFONIC ACID HAFNIUM(IV) SALT;HAFNIUM TRIFLATE;HAFNIUM TRIFLUOROMETHANESULFONATE;HAFNIUM(IV) TRIFLUOROMETHANESULFONATE;HAFNIUM (IV) TRIFLUOROMETHANESULPHONATE;HAFNIUM TRIFLUOROMETHANESULFONATE HYDRAT E;hafnium(iv) trifluoromethanesulfonate hydrate
5 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 1G
  • 5G
  • 25g
  • ManufacturerTCI Chemicals (India)
  • Product numberT1708
  • Product descriptionHafnium(IV) Trifluoromethanesulfonate
  • Packaging1G
  • Price₹2000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT1708
  • Product descriptionHafnium(IV) Trifluoromethanesulfonate
  • Packaging5G
  • Price₹5900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number469041
  • Product descriptionHafnium(IV) trifluoromethanesulfonate hydrate
  • Packaging1G
  • Price₹5830
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L19688-14
  • Product descriptionHafnium trifluoromethanesulfonate, 98%
  • Packaging25g
  • Price₹35350
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L19688-06
  • Product descriptionHafnium trifluoromethanesulfonate, 98%
  • Packaging5g
  • Price₹8123
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) T1708 Hafnium(IV) Trifluoromethanesulfonate 1G ₹2000 2022-05-26 Buy
TCI Chemicals (India) T1708 Hafnium(IV) Trifluoromethanesulfonate 5G ₹5900 2022-05-26 Buy
Sigma-Aldrich(India) 469041 Hafnium(IV) trifluoromethanesulfonate hydrate 1G ₹5830 2022-06-14 Buy
ALFA India ALF-L19688-14 Hafnium trifluoromethanesulfonate, 98% 25g ₹35350 2022-05-26 Buy
ALFA India ALF-L19688-06 Hafnium trifluoromethanesulfonate, 98% 5g ₹8123 2022-05-26 Buy

Properties

Melting point :>350 °C(lit.)
Flash point :None
solubility :Soluble in methyl cyanide, dicholomethane, dichloroethane, nitromethane, dioxane, terahydrofuran and toluene.
form :powder to crystal
color :White to Light yellow
Sensitive :Hygroscopic
Exposure limits :ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3 CAS DataBase Reference :161337-67-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Hafnium trifluoromethanesulfonate is a recyclable catalyst for the mononitration of o-nitrotoluene. It serves as a catalyst for homogeneous methoxycarbonylation and hydrocarboxylation reactions of phenylacetylene. It is also used as a reactant for direct Friedel-Crafts reactions of chromene hemiacetals, aminomethylation reactions under Lewis acidic conditions and prins-type cyclization reactions. It is also involved in the direct polycondensation of lactic acid. Further, it is used in cationic benzylation reactions, chemoselective thioacetalization and transthioacetalization of carbonyl compounds.

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