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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic ruthenium >Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium

Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium

Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Structure
  • ₹11025 - ₹49295.1
  • Product name: Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
  • CAS: 172222-30-9
  • MF: C43H73Cl2P2Ru
  • MW: 823.96
  • EINECS:629-485-2
  • MDL Number:MFCD01074452
  • Synonyms:Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium;Phenylmethylenebis(tricyclohexlPhosPhine)ruthenium chloride;GRUBB'S CATALYST 97%;Bis-(tricyclohexylphosphine)-benzylideneruthenium;Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(IV);Bis(tricyclohexylphosphine)benzylidine ruthenium(lV) dichloride;Grubbs (1st generation);Benzylidene-bis(tricyclohexylphosphine)dichlororutheniuM,Grubbs Catalyst 1st Generation
4 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 1gm
  • 1G
  • 5G
  • 5gm
  • ManufacturerSigma-Aldrich(India)
  • Product number579726
  • Product descriptionGrubbs Catalyst® M102 Umicore, 97%
  • Packaging1G
  • Price₹12321
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number579726
  • Product descriptionGrubbs Catalyst® M102 Umicore, 97%
  • Packaging5G
  • Price₹49295.1
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number G 2820
  • Product descriptionGrubbs catalyst, 1st generation 97%
  • Packaging5gm
  • Price₹45009
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number G 2820
  • Product descriptionGrubbs catalyst, 1st generation 97%
  • Packaging1gm
  • Price₹11025
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 579726 Grubbs Catalyst® M102 Umicore, 97% 1G ₹12321 2022-06-14 Buy
Sigma-Aldrich(India) 579726 Grubbs Catalyst® M102 Umicore, 97% 5G ₹49295.1 2022-06-14 Buy
ottokemi G 2820 Grubbs catalyst, 1st generation 97% 5gm ₹45009 2022-05-26 Buy
ottokemi G 2820 Grubbs catalyst, 1st generation 97% 1gm ₹11025 2022-05-26 Buy

Properties

Melting point :153 °C (dec.)(lit.)
storage temp. :2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Sparingly)
form :solid
color :Purple
Merck :13,4565
InChI :InChI=1S/2C18H33P.C7H5.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;2-6H;2*1H;/q;;-2;;;+2
InChIKey :PNPBGYBHLCEVMK-UHFFFAOYSA-L
SMILES :[Ru+4]([Cl-])([Cl-])(=[C-2]C1C=CC=CC=1)(P(C1CCCCC1)(C1CCCCC1)C1CCCCC1)P(C1CCCCC1)(C1CCCCC1)C1CCCCC1
CAS DataBase Reference :172222-30-9

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
GHS hazard pictograms P210, P240,P241, P280, P370+P378
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Description

First metathesis catalyst to be widely used in organic synthesis. Useful in Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, in Olefin cross metathesis (CM) and Ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions. Used to form stapled peptides.

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