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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Crown ether >18-Crown-6

18-Crown-6

18-Crown-6  Structure
  • ₹297 - ₹61408
  • Product name: 18-Crown-6
  • CAS: 17455-13-9
  • MF: C12H24O6
  • MW: 264.32
  • EINECS:241-473-5
  • MDL Number:MFCD00005113
  • Synonyms:18-CROWN-6;CROWN-18-5-ETHER;CROWN ETHER/18-CROWN-6;AKOS BBS-00004361;CROWN ETHER/18-CROWN-6 FOR SYNTHESIS;18 and crown ether;18-Crown-6 >=99.0%;18-Crown-6 99%
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  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India
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  • ottokemi

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  • ManufacturerTCI Chemicals (India)
  • Product numberC0860
  • Product description18-Crown 6-Ether min. 98.0 %
  • Packaging5G
  • Price₹2200
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberC0860
  • Product description18-Crown 6-Ether min. 98.0 %
  • Packaging25G
  • Price₹4700
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberC0860
  • Product description18-Crown 6-Ether min. 98.0 %
  • Packaging100G
  • Price₹14700
  • Updated2022-05-26
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.11684
  • Product descriptionCrown ether/18-Crown-6 for synthesis
  • Packaging2G
  • Price₹2260
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number28125
  • Product description18-Crown-6 purum, ≥99.0% (GC)
  • Packaging5G
  • Price₹3344.93
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.11684
  • Product descriptionCrown ether/18-Crown-6 for synthesis
  • Packaging5G
  • Price₹3600
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number186651
  • Product description18-Crown-6 99%
  • Packaging5G
  • Price₹5290
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number274984
  • Product description18-Crown-6 ≥99.0%
  • Packaging1G
  • Price₹7231.1
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number80833
  • Product description18-Crown-6 suitable for ion chromatography, ≥99.0% (GC)
  • Packaging10G
  • Price₹8649.18
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number28125
  • Product description18-Crown-6 purum, ≥99.0% (GC)
  • Packaging25G
  • Price₹10597.68
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number186651
  • Product description18-Crown-6 99%
  • Packaging25G
  • Price₹13000
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number8.11684
  • Product descriptionCrown ether/18-Crown-6 for synthesis
  • Packaging25G
  • Price₹13670
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number901591
  • Product description18-Crown-6 solution 1.0?M in THF
  • Packaging25ML
  • Price₹26437.73
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number28125
  • Product description18-Crown-6 purum, ≥99.0% (GC)
  • Packaging100G
  • Price₹28816.15
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number186651
  • Product description18-Crown-6 99%
  • Packaging100G
  • Price₹30550
  • Updated2022-06-14
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  • ManufacturerALFA India
  • Product numberALF-A11249-30
  • Product description18-Crown-6, 99%
  • Packaging250g
  • Price₹61408
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) C0860 18-Crown 6-Ether min. 98.0 % 5G ₹2200 2022-05-26 Buy
TCI Chemicals (India) C0860 18-Crown 6-Ether min. 98.0 % 25G ₹4700 2022-05-26 Buy
TCI Chemicals (India) C0860 18-Crown 6-Ether min. 98.0 % 100G ₹14700 2022-05-26 Buy
Sigma-Aldrich(India) 8.11684 Crown ether/18-Crown-6 for synthesis 2G ₹2260 2022-06-14 Buy
Sigma-Aldrich(India) 28125 18-Crown-6 purum, ≥99.0% (GC) 5G ₹3344.93 2022-06-14 Buy
Sigma-Aldrich(India) 8.11684 Crown ether/18-Crown-6 for synthesis 5G ₹3600 2022-06-14 Buy
Sigma-Aldrich(India) 186651 18-Crown-6 99% 5G ₹5290 2022-06-14 Buy
Sigma-Aldrich(India) 274984 18-Crown-6 ≥99.0% 1G ₹7231.1 2022-06-14 Buy
Sigma-Aldrich(India) 80833 18-Crown-6 suitable for ion chromatography, ≥99.0% (GC) 10G ₹8649.18 2022-06-14 Buy
Sigma-Aldrich(India) 28125 18-Crown-6 purum, ≥99.0% (GC) 25G ₹10597.68 2022-06-14 Buy
Sigma-Aldrich(India) 186651 18-Crown-6 99% 25G ₹13000 2022-06-14 Buy
Sigma-Aldrich(India) 8.11684 Crown ether/18-Crown-6 for synthesis 25G ₹13670 2022-06-14 Buy
Sigma-Aldrich(India) 901591 18-Crown-6 solution 1.0?M in THF 25ML ₹26437.73 2022-06-14 Buy
Sigma-Aldrich(India) 28125 18-Crown-6 purum, ≥99.0% (GC) 100G ₹28816.15 2022-06-14 Buy
Sigma-Aldrich(India) 186651 18-Crown-6 99% 100G ₹30550 2022-06-14 Buy
ALFA India ALF-A11249-30 18-Crown-6, 99% 250g ₹61408 2022-05-26 Buy

Properties

Melting point :42-45 °C(lit.)
Boiling point :116°C 0,2mm
Density :1,175 g/cm3
refractive index :1.4580 (estimate)
Flash point :>230 °F
storage temp. :Store below +30°C.
solubility :Chloroform (Slightly), Methanol (Very Slightly)
form :Crystals or Crystalline Mass or Liquid
color :White or clear colorless
Water Solubility :SOLUBLE
Sensitive :Hygroscopic
Merck :14,2602
BRN :1619616
Stability :Stable. Incompatible with strong acids, strong oxidizing agents.
InChIKey :XEZNGIUYQVAUSS-UHFFFAOYSA-N
CAS DataBase Reference :17455-13-9(CAS DataBase Reference)
NIST Chemistry Reference :1,4,7,10,13,16-Hexaoxacyclooctadecane(17455-13-9)
EPA Substance Registry System :1,4,7,10,13,16-Hexaoxacyclooctadecane (17455-13-9)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P501 Dispose of contents/container to..…

Description

18-Crown-6 is used as an efficient phase transfer catalyst and as a complexing agent with a variety of small cation. It is involved in the synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6. It facilitates the solubility of potassium permanganate in benzene, which is used for oxidizing the organic compounds. It is used to accelerate various substitution reactions as well as enhances the power of nucleophiles such as potassium acetate. It is utilized in the alkylation reactions in the presence of potassium carbonate, N-alkylation of glutarimide and succinimide with dimethylcarbonate. The complex formed by its reaction with potassium cyanide acts as a catalyst in the cyanosilylation of aldehydes, ketones and quinines with trimethylsilyl cyanide (TMSCN).

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