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ChemicalBook > Product Catalogue >Chemical Reagents >Silane reagent >N-(Trimethylsilyl)imidazole

N-(Trimethylsilyl)imidazole

N-(Trimethylsilyl)imidazole Structure
  • ₹890 - ₹46460.9
  • Product name: N-(Trimethylsilyl)imidazole
  • CAS: 18156-74-6
  • MF: C6H12N2Si
  • MW: 140.26
  • EINECS:242-040-3
  • MDL Number:MFCD00005280
  • Synonyms:N-Trimethylsilylimidazole, 95+%;1-Trimethysiylimidazole;1H-Imidazole, 1-(trimethylsilyl)-;n-trimethylsilylimidazole kit;sim kit;tms-imidazole(sim) kit;N-TRIMETHYSIYLIMIDAZOLE;1-(Trimethylsily)imidazole
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  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • Sigma-Aldrich
  • SRL

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  • 5ML
  • 5g
  • 10X1ML
  • 25ML
  • 25G
  • 50g
  • 50ML
  • 100g
  • 100ML
  • 250ML
  • 250g
  • 1KIT
  • ManufacturerALFA India
  • Product numberALF-A12512-06
  • Product description1-(Trimethylsilyl)imidazole, 97%
  • Packaging5g
  • Price₹1900
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-A12512-18
  • Product description1-(Trimethylsilyl)imidazole, 97%
  • Packaging50g
  • Price₹8746
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-A12512-22
  • Product description1-(Trimethylsilyl)imidazole, 97%
  • Packaging100g
  • Price₹14343
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-A12512-30
  • Product description1-(Trimethylsilyl)imidazole, 97%
  • Packaging250g
  • Price₹32982
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA5605
  • Product descriptionTMS-Imidazole (=N-Trimethylsilylimidazole) [for Gas Chromatography]
  • Packaging5ML
  • Price₹3200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT0585
  • Product descriptionN-Trimethylsilylimidazole [Trimethylsilylating Reagent]
  • Packaging25G
  • Price₹3300
  • Updated2022-05-26
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  • ManufacturerTCI Chemicals (India)
  • Product numberT0585
  • Product descriptionN-Trimethylsilylimidazole [Trimethylsilylating Reagent]
  • Packaging100G
  • Price₹8100
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number92751
  • Product description1-(Trimethylsilyl)imidazole ≥98.0%
  • Packaging250ML
  • Price₹46460.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.18204
  • Product descriptionN-(Trimethylsilyl)imidazole for synthesis
  • Packaging100ML
  • Price₹28840
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number394874
  • Product description1-(Trimethylsilyl)imidazole for GC derivatization, LiChropur?
  • Packaging25ML
  • Price₹22656.73
  • Updated2022-06-14
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  • ManufacturerSigma-Aldrich(India)
  • Product number394874
  • Product description1-(Trimethylsilyl)imidazole for GC derivatization, LiChropur?
  • Packaging10X1ML
  • Price₹17211.75
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number8.18204
  • Product descriptionN-(Trimethylsilyl)imidazole for synthesis
  • Packaging25ML
  • Price₹13650
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number153583
  • Product description1-(Trimethylsilyl)imidazole 96%
  • Packaging100ML
  • Price₹11691
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number92751
  • Product description1-(Trimethylsilyl)imidazole ≥98.0%
  • Packaging50ML
  • Price₹11636.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number394874
  • Product description1-(Trimethylsilyl)imidazole for GC derivatization, LiChropur?
  • Packaging5ML
  • Price₹8389.38
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number153583
  • Product description1-(Trimethylsilyl)imidazole 96%
  • Packaging25ML
  • Price₹3626.38
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-A12512-06 1-(Trimethylsilyl)imidazole, 97% 5g ₹1900 2022-05-26 Buy
ALFA India ALF-A12512-18 1-(Trimethylsilyl)imidazole, 97% 50g ₹8746 2022-05-26 Buy
ALFA India ALF-A12512-22 1-(Trimethylsilyl)imidazole, 97% 100g ₹14343 2022-05-26 Buy
ALFA India ALF-A12512-30 1-(Trimethylsilyl)imidazole, 97% 250g ₹32982 2022-05-26 Buy
TCI Chemicals (India) A5605 TMS-Imidazole (=N-Trimethylsilylimidazole) [for Gas Chromatography] 5ML ₹3200 2022-05-26 Buy
TCI Chemicals (India) T0585 N-Trimethylsilylimidazole [Trimethylsilylating Reagent] 25G ₹3300 2022-05-26 Buy
TCI Chemicals (India) T0585 N-Trimethylsilylimidazole [Trimethylsilylating Reagent] 100G ₹8100 2022-05-26 Buy
Sigma-Aldrich(India) 92751 1-(Trimethylsilyl)imidazole ≥98.0% 250ML ₹46460.9 2022-06-14 Buy
Sigma-Aldrich(India) 8.18204 N-(Trimethylsilyl)imidazole for synthesis 100ML ₹28840 2022-06-14 Buy
Sigma-Aldrich(India) 394874 1-(Trimethylsilyl)imidazole for GC derivatization, LiChropur? 25ML ₹22656.73 2022-06-14 Buy
Sigma-Aldrich(India) 394874 1-(Trimethylsilyl)imidazole for GC derivatization, LiChropur? 10X1ML ₹17211.75 2022-06-14 Buy
Sigma-Aldrich(India) 8.18204 N-(Trimethylsilyl)imidazole for synthesis 25ML ₹13650 2022-06-14 Buy
Sigma-Aldrich(India) 153583 1-(Trimethylsilyl)imidazole 96% 100ML ₹11691 2022-06-14 Buy
Sigma-Aldrich(India) 92751 1-(Trimethylsilyl)imidazole ≥98.0% 50ML ₹11636.88 2022-06-14 Buy
Sigma-Aldrich(India) 394874 1-(Trimethylsilyl)imidazole for GC derivatization, LiChropur? 5ML ₹8389.38 2022-06-14 Buy
Sigma-Aldrich(India) 153583 1-(Trimethylsilyl)imidazole 96% 25ML ₹3626.38 2022-06-14 Buy

Properties

Melting point :-42 °C
Boiling point :93-94 °C14 mm Hg(lit.)
Density :0.957 g/mL at 20 °C
refractive index :n20/D 1.475(lit.)
Flash point :42 °F
storage temp. :Store below +30°C.
solubility :Chloroform
form :Liquid
pka :7.96±0.10(Predicted)
Specific Gravity :0.956
color :Clear colorless to yellow
Water Solubility :decomposes
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
BRN :606148
Stability :Air and Moisture Sensitive
InChIKey :YKFRUJSEPGHZFJ-UHFFFAOYSA-N
CAS DataBase Reference :18156-74-6(CAS DataBase Reference)
NIST Chemistry Reference :1h-Imidazole, 1-(trimethylsilyl)-(18156-74-6)
EPA Substance Registry System :1H-Imidazole, 1-(trimethylsilyl)- (18156-74-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1-(Trimethylsilyl)imidazole acts as a silylating agent for alcohols, carbohydrates and 1,3-dicarbonyl compounds. It is a derivatization reagent used for selective silylation of hydroxyl groups and carboxylic acid without affecting the amino group. It employed as an intermediate for the synthesis of imidazole derivatives. It plays an essential role to synthesize polysubstituted chiral spirotetrahydropyrans. It is also used in the quantification of pintol after derivatization by gas chromatography/ mass spectrometry.

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