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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >4-THIOANISOLEMAGNESIUM BROMIDE

4-THIOANISOLEMAGNESIUM BROMIDE

4-THIOANISOLEMAGNESIUM BROMIDE Structure
  • ₹13985.9
  • Product name: 4-THIOANISOLEMAGNESIUM BROMIDE
  • CAS: 18620-04-7
  • MF: C7H7BrMgS
  • MW: 227.4
  • EINECS:
  • MDL Number:MFCD00672010
  • Synonyms:4-THIOANISOLEMAGNESIUM BROMIDE, 0.5M SOLUT TION IN TETRAHYDROFURAN;4-THIOANISOLEMAGNESIUM BROMIDE;4-thioanisolemagnesium bromide solution;4-Thioanisolemagnesium bromide, 0.5M solution in THF, AcroSeal;4-Thioanisolemagnesium bromide,0.5M solutionin THF;4-ThioanisoleMagnesiuM broMide, 0.5 M solution in THF, J&KSeal;4-(Methylthio)phenylmagnesium bromide;magnesium,methylsulfanylbenzene,bromide
Price1 Properties Safety Information Description
1 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 50ML
  • ManufacturerSigma-Aldrich(India)
  • Product number561762
  • Product description4-Thioanisolemagnesium bromide solution 0.5?M in THF
  • Packaging50ML
  • Price₹13985.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 561762 4-Thioanisolemagnesium bromide solution 0.5?M in THF 50ML ₹13985.9 2022-06-14 Buy

Properties

Boiling point :65 °C
Density :0.965 g/mL at 25 °C
Flash point :<1 °F
storage temp. :2-8°C
form :Solution
color :Clear yellow to brown

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.

Description

4-Thioanisolemagnesium bromide can be used to prepare:
  • 3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.
  • (1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl?D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.

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