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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organomagnesium >PHENYLMAGNESIUM BROMIDE

PHENYLMAGNESIUM BROMIDE

PHENYLMAGNESIUM BROMIDE Structure
  • ₹1557 - ₹47835.68
  • Product name: PHENYLMAGNESIUM BROMIDE
  • CAS: 100-58-3
  • MF: C6H5BrMg
  • MW: 181.31
  • EINECS:202-867-2
  • MDL Number:MFCD00000038
  • Synonyms:bromophenylmagnesium;Phenylmagnesium bromide, 2.8M solution in Diethyl ether;PHENYLMAGNESIUM BROMIDE, 1.0-1.2M in TETRAHYDROFURAN;Phenylmagnesiumbromide,3Minether;Magnesium, bromophenyl-;phenylmagnesium bromide, 3m in ether, packaged under argon in resealable chemseal;Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSealTM bottles;Phenylmagnesium Bromide (32% in Tetrahydrofuran, ca. 2mol/L)
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Brand

  • Sigma-Aldrich
  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 50ML
  • 4X25ML
  • 100ML
  • 250G
  • 500mL
  • 800ML
  • 0.5mol
  • ManufacturerSigma-Aldrich
  • Product number171565
  • Product descriptionPhenylmagnesium bromide solution 3.0?M in diethyl ether
  • Packaging50ML
  • Price₹3583.08
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging50ML
  • Price₹4319.18
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging100ML
  • Price₹5390.85
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging4X25ML
  • Price₹6770
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging800ML
  • Price₹11907.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number171565
  • Product descriptionPhenylmagnesium bromide solution 3.0?M in diethyl ether
  • Packaging800ML
  • Price₹16075.13
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042859-JT
  • Product descriptionPhenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging0.5mol
  • Price₹1557
  • Updated2022-05-26
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  • ManufacturerALFA India
  • Product numberALF-H54729-AE
  • Product descriptionPhenylmagnesium bromide, 3M in 2-MeTHF
  • Packaging100mL
  • Price₹4013
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042859-AE
  • Product descriptionPhenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging100mL
  • Price₹4267
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-087326-AE
  • Product descriptionPhenylmagnesium bromide, 3M in ether
  • Packaging100mL
  • Price₹5769
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042859-AP
  • Product descriptionPhenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles
  • Packaging500mL
  • Price₹14451
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-087326-AP
  • Product descriptionPhenylmagnesium bromide, 3M in ether
  • Packaging500mL
  • Price₹14466
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberP2025
  • Product descriptionPhenylmagnesium Bromide (16% in Tetrahydrofuran, ca. 1mol/L)
  • Packaging250G
  • Price₹6900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number171565
  • Product descriptionPhenylmagnesium bromide solution 3.0?M in diethyl ether
  • Packaging50ML
  • Price₹3583.08
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging50ML
  • Price₹4319.18
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number331376
  • Product descriptionPhenylmagnesium bromide solution 1.0?M in THF
  • Packaging100ML
  • Price₹5390.85
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 171565 Phenylmagnesium bromide solution 3.0?M in diethyl ether 50ML ₹3583.08 2022-06-14 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0?M in THF 50ML ₹4319.18 2022-06-14 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0?M in THF 100ML ₹5390.85 2022-06-14 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0?M in THF 4X25ML ₹6770 2022-06-14 Buy
Sigma-Aldrich 331376 Phenylmagnesium bromide solution 1.0?M in THF 800ML ₹11907.5 2022-06-14 Buy
Sigma-Aldrich 171565 Phenylmagnesium bromide solution 3.0?M in diethyl ether 800ML ₹16075.13 2022-06-14 Buy
ALFA India ALF-042859-JT Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles 0.5mol ₹1557 2022-05-26 Buy
ALFA India ALF-H54729-AE Phenylmagnesium bromide, 3M in 2-MeTHF 100mL ₹4013 2022-05-26 Buy
ALFA India ALF-042859-AE Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles 100mL ₹4267 2022-05-26 Buy
ALFA India ALF-087326-AE Phenylmagnesium bromide, 3M in ether 100mL ₹5769 2022-05-26 Buy
ALFA India ALF-042859-AP Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles 500mL ₹14451 2022-05-26 Buy
ALFA India ALF-087326-AP Phenylmagnesium bromide, 3M in ether 500mL ₹14466 2022-05-26 Buy
TCI Chemicals (India) P2025 Phenylmagnesium Bromide (16% in Tetrahydrofuran, ca. 1mol/L) 250G ₹6900 2022-05-26 Buy
Sigma-Aldrich(India) 171565 Phenylmagnesium bromide solution 3.0?M in diethyl ether 50ML ₹3583.08 2022-06-14 Buy
Sigma-Aldrich(India) 331376 Phenylmagnesium bromide solution 1.0?M in THF 50ML ₹4319.18 2022-06-14 Buy
Sigma-Aldrich(India) 331376 Phenylmagnesium bromide solution 1.0?M in THF 100ML ₹5390.85 2022-06-14 Buy

Properties

Melting point :153-154 °C
Density :1.134 g/mL at 25 °C
Flash point :−40 °F
storage temp. :water-free area
solubility :Miscible with tetrahydrofuran.
form :Liquid
color :Yellow to brown
Specific Gravity :1.14
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :3588849
InChIKey :ANRQGKOBLBYXFM-UHFFFAOYSA-M
CAS DataBase Reference :100-58-3(CAS DataBase Reference)
EPA Substance Registry System :Magnesium, bromophenyl- (100-58-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

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