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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Borane >4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE

4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE

4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE Structure
  • ₹4600 - ₹10879.13
  • Product name: 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE
  • CAS: 195062-61-4
  • MF: C12H16BClO2
  • MW: 238.52
  • EINECS:
  • MDL Number:MFCD05663875
  • Synonyms:2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;4-Chlorobenzeneboronic acid, pinacol ester;4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE;4-CHLOROPHENYLBORONIC ACID, PINACOL ESTER;4-Chlorophenylboronic acid pinacol ester 97%;Pinacol (4-chlorophenyl)boronate;Pinac;1,3,2-Dioxaborolane, 2-(4-chlorophenyl)-4,4,5,5-tetramethyl-
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 10G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberC3500
  • Product description2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane min. 98.0 %
  • Packaging5G
  • Price₹4600
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberC3500
  • Product description2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane min. 98.0 %
  • Packaging25G
  • Price₹8000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number632724
  • Product description4-Chlorophenylboronic acid pinacol ester 97%
  • Packaging10G
  • Price₹10879.13
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number632724
  • Product description4-Chlorophenylboronic acid pinacol ester 97%
  • Packaging5G
  • Price₹5932.1
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) C3500 2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane min. 98.0 % 5G ₹4600 2022-05-26 Buy
TCI Chemicals (India) C3500 2-(4-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane min. 98.0 % 25G ₹8000 2022-05-26 Buy
Sigma-Aldrich(India) 632724 4-Chlorophenylboronic acid pinacol ester 97% 10G ₹10879.13 2022-06-14 Buy
Sigma-Aldrich(India) 632724 4-Chlorophenylboronic acid pinacol ester 97% 5G ₹5932.1 2022-06-14 Buy

Properties

Melting point :50-55 °C(lit.)
Boiling point :308.7±25.0 °C(Predicted)
Density :1.10±0.1 g/cm3(Predicted)
Flash point :>230 °F
storage temp. :2-8°C
solubility :soluble in Methanol
form :Solid
color :White to pale brown
InChIKey :NYARTXMDWRAVIX-UHFFFAOYSA-N
CAS DataBase Reference :195062-61-4

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:
P273 Avoid release to the environment.

Description

4-Chlorophenylboronic acid pinacol ester can be used as a reagent in Suzuki-Miyaura cross-coupling reaction to form C-C bonds by reacting with different aryl halides over palladium catalysts.
It can also be used as a reactant:
  • To prepare 2-(4-chlorophenyl)-4H-chromen-4-one by treating with 4-chromanone via one-pot palladium-catalyzed dehydrogenation and oxidative boron-Heck coupling reaction.
  • In the ligand-enabled C-H bond activation reaction in the presence of a palladium catalyst.
  • To synthesize biaryl amides via Cu-catalyzed C-H bond coupling of aryl arylamides.


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