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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Structure
  • ₹9956.7 - ₹36652.2
  • Product name: (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
  • CAS: 213343-65-8
  • MF: C22H40BF4P2Rh-
  • MW: 556.21
  • EINECS:
  • MDL Number:MFCD32853739
  • Synonyms:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%;(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh;(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh;(S,S)-ME-BPE-RH;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-BPE-RH
2 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 100MG
  • 500MG
  • ManufacturerSigma-Aldrich(India)
  • Product number675547
  • Product description1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging100MG
  • Price₹9956.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number675547
  • Product description1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate
  • Packaging500MG
  • Price₹36652.2
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 675547 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate 100MG ₹9956.7 2022-06-14 Buy
Sigma-Aldrich(India) 675547 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate 500MG ₹36652.2 2022-06-14 Buy

Properties

Melting point :152.2-156.3 °C
form :Crystalline Powder
color :Orange to red to brown
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Asymmetric hydrogenation

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