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(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Structure
  • ₹8876.5 - ₹39565.38
  • Product name: (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
  • CAS: 259259-80-8
  • MF: C32H38CoN2O4
  • MW: 573.59
  • EINECS:
  • MDL Number:MFCD06797062
  • Synonyms:(S)-AMAC;Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-;(S,S)-AMAC;(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II);CID 135483535;(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II);(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II), CAS 259259-80-8
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 500MG
  • ManufacturerTCI Chemicals (India)
  • Product numberB2315
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging100MG
  • Price₹23800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number708844
  • Product description(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
  • Packaging100MG
  • Price₹8876.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number708844
  • Product description(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
  • Packaging500MG
  • Price₹39565.38
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B2315 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 100MG ₹23800 2022-05-26 Buy
Sigma-Aldrich(India) 708844 (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) 100MG ₹8876.5 2022-06-14 Buy
Sigma-Aldrich(India) 708844 (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) 500MG ₹39565.38 2022-06-14 Buy

Properties

Melting point :242-246°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :powder to crystal
color :Orange to Brown
optical activity :[α]/D 309°, c = 0.1 in chloroform

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Catalyst for:
  • Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
  • Enantioselective borohydride reduction
  • Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
  • Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones

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