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ChemicalBook > Product Catalogue >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon halides >[Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene Structure
  • ₹2667 - ₹14906.03
  • Product name: [Bis(trifluoroacetoxy)iodo]benzene
  • CAS: 2712-78-9
  • MF: C10H5F6IO4
  • MW: 430.04
  • EINECS:220-308-0
  • MDL Number:MFCD00009672
  • Synonyms:IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE);IODINE, PHENYLBIS(TRIFLUOROACETATO)-;IODOBENZENE BIS(TRIFLUOROACETATE);IODOBENZENE I,I-BIS(TRIFLUOROACETATE);BIS(TRIFLUORACETOXY)- IODOBENZENE;[BIS(TRIFLUOROACETOXY)IODO]BENZENE;[Bis(trifluoroacetoxy)](phenyl)iodane;Iodobenzene 1,1-bis(trifluoroacetate)
Price8 Properties Safety Information Description
8 prices
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Brand

  • Sigma-Aldrich
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 5g
  • 10G
  • 25g
  • 50G
  • ManufacturerSigma-Aldrich
  • Product number232130
  • Product description[Bis(trifluoroacetoxy)iodo]benzene 97%
  • Packaging10G
  • Price₹3344.93
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number232130
  • Product description[Bis(trifluoroacetoxy)iodo]benzene 97%
  • Packaging50G
  • Price₹14906.03
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number232130
  • Product description[Bis(trifluoroacetoxy)iodo]benzene 97%
  • Packaging10G
  • Price₹3344.93
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number15230
  • Product description[Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT)
  • Packaging10G
  • Price₹4849.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number15230
  • Product description[Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT)
  • Packaging50G
  • Price₹14256.53
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number232130
  • Product description[Bis(trifluoroacetoxy)iodo]benzene 97%
  • Packaging50G
  • Price₹14906.03
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L15141-14
  • Product description[Bis(trifluoroacetoxy)iodo]benzene, 97%
  • Packaging25g
  • Price₹8444
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L15141-06
  • Product description[Bis(trifluoroacetoxy)iodo]benzene, 97%
  • Packaging5g
  • Price₹2667
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 10G ₹3344.93 2022-06-14 Buy
Sigma-Aldrich 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 50G ₹14906.03 2022-06-14 Buy
Sigma-Aldrich(India) 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 10G ₹3344.93 2022-06-14 Buy
Sigma-Aldrich(India) 15230 [Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT) 10G ₹4849.6 2022-06-14 Buy
Sigma-Aldrich(India) 15230 [Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT) 50G ₹14256.53 2022-06-14 Buy
Sigma-Aldrich(India) 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 50G ₹14906.03 2022-06-14 Buy
ALFA India ALF-L15141-14 [Bis(trifluoroacetoxy)iodo]benzene, 97% 25g ₹8444 2022-05-26 Buy
ALFA India ALF-L15141-06 [Bis(trifluoroacetoxy)iodo]benzene, 97% 5g ₹2667 2022-05-26 Buy

Properties

Melting point :121-125 °C(lit.)
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form :Crystalline Powder
color :White to pale yellow
Water Solubility :insoluble
Sensitive :Moisture & Light Sensitive
BRN :764767
Stability :Air and Moisture Sensitive
CAS DataBase Reference :2712-78-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

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Suppliers and manufacturers

GLR Innovations ADVENT CHEMBIO PRIVATE LIMITED Infinium Pharmachem Limited ORGANO FINE CHEMICALS JSK Chemicals VASIN BIO LIFE SCIENCES PVT LTD Infinium Pharmachem Private Limited Organo Fine Chemicals CHEMSWORTH CLEARSYNTH LABS LTD.