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ChemicalBook > Product Catalog >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon halides >[Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene Structure
CAS No.
2712-78-9
Chemical Name:
[Bis(trifluoroacetoxy)iodo]benzene
Synonyms
PIFA;BTI;DFAIB;Bacillus thuringiensis israelensis;[Bis(trifluoroacetox;LABOTEST-BB LT00454809;uoroacetoxy)iodo]benzene;[Bis(trifluoroacetoxy)iodo]ben;1Bis-trifluoroacetoxyiodobenzene;BIS(TRIFLUORACETOXY)- IODOBENZENE
CBNumber:
CB9419191
Molecular Formula:
C10H5F6IO4
Molecular Weight:
430.04
MOL File:
2712-78-9.mol
MSDS File:
SDS
Modify Date:
2024/8/8 13:40:43
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[Bis(trifluoroacetoxy)iodo]benzene Properties

Melting point 121-125 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form Crystalline Powder
color White to pale yellow
Water Solubility insoluble
Sensitive Moisture & Light Sensitive
BRN 764767
Stability Air and Moisture Sensitive
CAS DataBase Reference 2712-78-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
F  4.10-8-9-21
Hazard Note  Irritant/Keep Cold
HazardClass  IRRITANT, KEEP COLD, LIGHT SENSITIVE
HS Code  29036990
NFPA 704
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[Bis(trifluoroacetoxy)iodo]benzene price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 2712-78-9 10G ₹3344.93 2022-06-14 Buy
Sigma-Aldrich(India) 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 2712-78-9 10G ₹3344.93 2022-06-14 Buy
Sigma-Aldrich 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 2712-78-9 50G ₹14906.03 2022-06-14 Buy
Sigma-Aldrich(India) 232130 [Bis(trifluoroacetoxy)iodo]benzene 97% 2712-78-9 50G ₹14906.03 2022-06-14 Buy
Sigma-Aldrich(India) 15230 [Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT) 2712-78-9 10G ₹4849.6 2022-06-14 Buy
Product number Packaging Price Buy
232130 10G ₹3344.93 Buy
232130 10G ₹3344.93 Buy
232130 50G ₹14906.03 Buy
232130 50G ₹14906.03 Buy
15230 10G ₹4849.6 Buy

[Bis(trifluoroacetoxy)iodo]benzene Chemical Properties,Uses,Production

Chemical Properties

White to pale yellow crystalline powder

Uses

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Purification Methods

Crystallise the iodo compound from warm trifluoroacetic acid and dry it over NaOH pellets. Recrystallise it also from Me2CO/pet ether. Its melting point depends on the heating rate. [Spyroudis & Varvoglis Synthesis 445 1975, application: Almond et al. Org Synth 66 132 1988.]

[Bis(trifluoroacetoxy)iodo]benzene Preparation Products And Raw materials

Raw materials

Iodobenzene Hexane Hydrogen peroxide Sodium percarbonate Trifluoroacetic anhydride
Dichloromethane
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Preparation Products

T-BUTYL TRIFLUOROACETATE

[Bis(trifluoroacetoxy)iodo]benzene Suppliers

Global( 334)Suppliers
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GLR Innovations +91 9891111994 New Delhi, India 4542 58 Inquiry
ADVENT CHEMBIO PRIVATE LIMITED +91-9821524116 +91-9821524116 Mumbai, India 353 58 Inquiry
Infinium Pharmachem Limited +91-2692238849 +91-2692238850 Gujarat, India 65 58 Inquiry
ORGANO FINE CHEMICALS +91-91-22-42128300 +91-2242128300 Mumbai, India 258 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
Infinium Pharmachem Private Limited 09126922388 Gujarat, India 51 58 Inquiry
VASIN BIO LIFE SCIENCES PVT LTD 9491644688 Hyderabad, India 2096 58 Inquiry
Organo Fine Chemicals +91 (22) 2201-6968 / 2206-7521 New Delhi, India 266 60 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Supplier Advantage
GLR Innovations 58
ADVENT CHEMBIO PRIVATE LIMITED 58
Infinium Pharmachem Limited 58
ORGANO FINE CHEMICALS 58
JSK Chemicals 58
Infinium Pharmachem Private Limited 58
VASIN BIO LIFE SCIENCES PVT LTD 58
Organo Fine Chemicals 60
CHEMSWORTH 30
CLEARSYNTH LABS LTD. 58

[Bis(trifluoroacetoxy)iodo]benzene Spectrum

[Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)1HNMR[Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)IR1[Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)IR2[Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)Raman

2712-78-9([Bis(trifluoroacetoxy)iodo]benzene)Related Search:

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IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) IODINE, PHENYLBIS(TRIFLUOROACETATO)- IODOBENZENE BIS(TRIFLUOROACETATE) IODOBENZENE I,I-BIS(TRIFLUOROACETATE) BIS(TRIFLUORACETOXY)- IODOBENZENE [BIS(TRIFLUOROACETOXY)IODO]BENZENE [Bis(trifluoroacetoxy)](phenyl)iodane Iodobenzene 1,1-bis(trifluoroacetate) [Bis(trifluoroacetoxy)iodo]benzene purum, >=95.0% (AT) [Bis(trifluoroacetoxy)iodo]benzene SynonyMs Phenylbis(trifluoroacetato-O)iodine [phenyl-(2,2,2-trifluoroacetyl)oxy-3-iodanyl] 2,2,2-trifluoroacetate BTI~Iodosobenzene bis(trifluoroacetate)~Phenyliodine(III) bis(trifluoroacetate)~PIFA phenylbis(trifluoroacetato-O)iodine Bis-Trifluoroacetoxyiodobenzene99% Bis-Trifluoroacetoxyiodobenzene 99% Iodosobenzene-bis(trifluoroacetate) Phenyliodine(III)bis(trifluoroacetate) Bis(trifluoroacetoxy)iodoübenzene, 97% BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA [Bis(trifluoroacetoxy)iodo(III)]benzene [Di(trifluoroacetoxy)iodo(III)]benzene Bis(trifluoroacetic acid)phenyliodine(III) salt Phenylbis(trifluoroacetyloxy) iodine(III) Iodine, phenylbis(trifluoroacetato-.kappa.O)- bis(I,I-trifluoroacetoxy)iodobenzene [Bis(trifluoroacetoxy)iodo]benzene,98% 1Bis-trifluoroacetoxyiodobenzene [Bis(trifluoroethoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene,BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA [Bis(trifluoroacetox [Bis(trifluoroacetoxy)iodo]benzene, 98% 10GR [Bis(trifluoroacetoxy)iodo]benzene, 98% 50GR LABOTEST-BB LT00454809 BIS(TRIFLUOROACETOXY)IODOBENZENE FOR SYN [Bis(trifluoroacetoxy)iodo]ben [phenyl-(2,2,2-trifluoroacetyl)oxy-λ3-iodanyl] 2,2,2-trifluoroacetate uoroacetoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene, 98%, for synthesis [Bis(trifluoroacetoxy)iodo]benzene > Iodine, phenylbis(2,2,2-trifluoroacetato-κO)- [Bis(trifluoroacetoxy)iodo]benzene ISO 9001：2015 REACH [phenyl-(2,2,2-trifluoroacetyl)oxy- BTI DFAIB Bacillus thuringiensis israelensis PIFA 2712-78-9 C10H5F6IO4 C10H5O4F6I CF3CO22IC6H5 C10F6H5I1O4 C10H9F6IO2 C10H3F6IO4 Oxidation Synthetic Reagents Hypervalent Iodine Carbazoles