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ChemicalBook > Product Catalogue >Organic Chemistry >Hydrocarbons and derivatives >Cyclic hydrocarbons >3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE Structure
  • ₹3826 - ₹45829.2
  • Product name: 3-BROMOCYCLOHEXENE
  • CAS: 1521-51-3
  • MF: C6H9Br
  • MW: 161.04
  • EINECS:
  • MDL Number:MFCD00013775
  • Synonyms:1-Bromo-2-cyclohexene;2-Cyclohexenyl bromide;3-Bromo-1-cyclohexene;1,2,3,4-TETRAHYDROBROMOBENZENE;2-CYCLOHEXEN-1-YL BROMIDE;(+/-)-3-BROMOCYCLOHEXENE;3-BROMOCYCLOHEXENE;TIMTEC-BB SBB007864
8 prices
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5ML
  • 5g
  • 10ML
  • 25ML
  • 25g
  • 50ML
  • 100g
  • 250ML
  • ManufacturerALFA India
  • Product numberALF-A10370-06
  • Product description3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide
  • Packaging5g
  • Price₹3826
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A10370-14
  • Product description3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide
  • Packaging25g
  • Price₹15639
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A10370-22
  • Product description3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide
  • Packaging100g
  • Price₹45267
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB0943
  • Product description3-Bromocyclohexene min. 94.0 %
  • Packaging5ML
  • Price₹9500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB0943
  • Product description3-Bromocyclohexene min. 94.0 %
  • Packaging25ML
  • Price₹37300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging10ML
  • Price₹6298.35
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging50ML
  • Price₹21237.15
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number333549
  • Product description3-Bromocyclohexene technical grade, 90%
  • Packaging250ML
  • Price₹45829.2
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-A10370-06 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide 5g ₹3826 2022-05-26 Buy
ALFA India ALF-A10370-14 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide 25g ₹15639 2022-05-26 Buy
ALFA India ALF-A10370-22 3-Bromocyclohexene, 95%, stab. with 300-1000ppm Propylene oxide 100g ₹45267 2022-05-26 Buy
TCI Chemicals (India) B0943 3-Bromocyclohexene min. 94.0 % 5ML ₹9500 2022-05-26 Buy
TCI Chemicals (India) B0943 3-Bromocyclohexene min. 94.0 % 25ML ₹37300 2022-05-26 Buy
Sigma-Aldrich(India) 333549 3-Bromocyclohexene technical grade, 90% 10ML ₹6298.35 2022-06-14 Buy
Sigma-Aldrich(India) 333549 3-Bromocyclohexene technical grade, 90% 50ML ₹21237.15 2022-06-14 Buy
Sigma-Aldrich(India) 333549 3-Bromocyclohexene technical grade, 90% 250ML ₹45829.2 2022-06-14 Buy

Properties

Melting point :131-134 °C
Boiling point :57-58 °C/12 mmHg (lit.)
Density :1.4 g/mL at 25 °C (lit.)
refractive index :n20/D 1.528(lit.)
Flash point :130 °F
storage temp. :-20°C
form :Solid
color :White to off-white
Water Solubility :Not miscible or difficult to mix in water.
BRN :635953
InChIKey :AJKDUJRRWLQXHM-UHFFFAOYSA-N
CAS DataBase Reference :1521-51-3(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

In peptide synthesis, can be used to protect the hydroxyl group of serine and threonine as the cyclohexyl (Chx) ether, by reaction with the sodium alkoxide (generated with NaH), followed by hydrogenation. The group is stable to TFA and 20% piperidine in DMF, but can be cleaved with TfOH in TFA, in the presence of thioanisole as a cation scavenger. It is also used in the synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine.1 It was also used in the synthesis of enantiopure cyclohexitols such as muco-quercitol, D-chiro-inocitol and allo-inocitol.

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