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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >aliphatic ketones >3-Butyn-2-one

3-Butyn-2-one

3-Butyn-2-one Structure
  • ₹4100 - ₹59485
  • Product name: 3-Butyn-2-one
  • CAS: 1423-60-5
  • MF: C4H4O
  • MW: 68.07
  • EINECS:215-834-2
  • MDL Number:MFCD00008775
  • Synonyms:Methyl ethynyl ketone;ETHYNYL METHYL KETONE;1-BUTYN-3-ONE;1-BUTYNE-3-ONE;3-BUTYNE-2-ONE;3-BUTYN-2-ONE;3-Butyn-2-one 99%;3-BUTYN-2-ONE, 98+%
7 prices
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1g
  • 2.5ML
  • 5g
  • 10ML
  • 25g
  • ManufacturerALFA India
  • Product numberALF-L05527-03
  • Product description3-Butyn-2-one, 98%
  • Packaging1g
  • Price₹5106
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L05527-06
  • Product description3-Butyn-2-one, 98%
  • Packaging5g
  • Price₹15469
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L05527-14
  • Product description3-Butyn-2-one, 98%
  • Packaging25g
  • Price₹59485
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2393
  • Product description3-Butyn-2-one min. 97.0 %
  • Packaging1G
  • Price₹4100
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2393
  • Product description3-Butyn-2-one min. 97.0 %
  • Packaging5G
  • Price₹11800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number161314
  • Product description3-Butyn-2-one 95%
  • Packaging2.5ML
  • Price₹28253.25
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number161314
  • Product description3-Butyn-2-one 95%
  • Packaging10ML
  • Price₹48799.1
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L05527-03 3-Butyn-2-one, 98% 1g ₹5106 2022-05-26 Buy
ALFA India ALF-L05527-06 3-Butyn-2-one, 98% 5g ₹15469 2022-05-26 Buy
ALFA India ALF-L05527-14 3-Butyn-2-one, 98% 25g ₹59485 2022-05-26 Buy
TCI Chemicals (India) B2393 3-Butyn-2-one min. 97.0 % 1G ₹4100 2022-05-26 Buy
TCI Chemicals (India) B2393 3-Butyn-2-one min. 97.0 % 5G ₹11800 2022-05-26 Buy
Sigma-Aldrich(India) 161314 3-Butyn-2-one 95% 2.5ML ₹28253.25 2022-06-14 Buy
Sigma-Aldrich(India) 161314 3-Butyn-2-one 95% 10ML ₹48799.1 2022-06-14 Buy

Properties

Boiling point :85 °C(lit.)
Density :0.87 g/mL at 25 °C(lit.)
refractive index :n20/D 1.406(lit.)
Flash point :28 °F
storage temp. :0-6°C
form :Liquid
Specific Gravity :0.870
color :Clear yellow to orange-brown
Water Solubility :It is soluble in water.
BRN :605353
CAS DataBase Reference :1423-60-5(CAS DataBase Reference)
NIST Chemistry Reference :3-Butyn-2-one(1423-60-5)
EPA Substance Registry System :3-Butyn-2-one (1423-60-5)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

3-Butyn-2-one was used in the synthesis of clerodane diterpenoid (+/-)-sacacarin. It was used as substrate in stereoselective, conjugate arylation mediated by gallium(III) chloride leading to (E)-α,β-unsaturated ketones. 3-Butyn-2-one undergoes asymmetric double-Michael reaction with ortho-tosylamidophenyl malonate catalyzed by chiral aminophosphines to yield indolines2. It undergoes double Michael reaction with nitrogen-containing tethered diacid to give pipecolic acid derivatives. 3-Butyn-2-one, is used as a reactant with Dimethyl- acetone-1,3-dicarboxyl-ate, under mild conditions to give a benzenoid product via a Michael addition - aldol cyclization process.

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