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ChemicalBook > Product Catalogue >Pharmaceutical intermediates >Heterocyclic compound >Pyridine compound >Bromopyridine >3-Pyridyl bromide

3-Pyridyl bromide

3-Pyridyl bromide Structure
  • ₹2100.05 - ₹9655.9
  • Product name: 3-Pyridyl bromide
  • CAS: 626-55-1
  • MF: C5H4BrN
  • MW: 158
  • EINECS:210-952-0
  • MDL Number:MFCD00006373
  • Synonyms:Pyridine, 3-bromo-;5-BROMO PYRIDINE;3-pyridyl bromide;AURORA KA-875;TIMTEC-BB SBB003998;3-bromo-pyridin ;3-Bromopyridine 5-Bromo Pyridine;3-Bromopyridine, 98+%
5 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • 100G
  • ManufacturerTCI Chemicals (India)
  • Product numberB0651
  • Product description3-Bromopyridine (stabilized with Copper chip) min. 98.0 %
  • Packaging25G
  • Price₹3300
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB0651
  • Product description3-Bromopyridine (stabilized with Copper chip) min. 98.0 %
  • Packaging100G
  • Price₹8300
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberB80208
  • Product description3-Bromopyridine 99%
  • Packaging5G
  • Price₹2100.05
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberB80208
  • Product description3-Bromopyridine 99%
  • Packaging25G
  • Price₹6040.35
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberB80208
  • Product description3-Bromopyridine 99%
  • Packaging100G
  • Price₹9655.9
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B0651 3-Bromopyridine (stabilized with Copper chip) min. 98.0 % 25G ₹3300 2022-05-26 Buy
TCI Chemicals (India) B0651 3-Bromopyridine (stabilized with Copper chip) min. 98.0 % 100G ₹8300 2022-05-26 Buy
Sigma-Aldrich(India) B80208 3-Bromopyridine 99% 5G ₹2100.05 2022-06-14 Buy
Sigma-Aldrich(India) B80208 3-Bromopyridine 99% 25G ₹6040.35 2022-06-14 Buy
Sigma-Aldrich(India) B80208 3-Bromopyridine 99% 100G ₹9655.9 2022-06-14 Buy

Properties

Melting point :-27°C
Boiling point :173 °C (lit.)
Density :1.64 g/mL at 25 °C (lit.)
vapor pressure :1.64hPa at 25℃
refractive index :n20/D 1.571(lit.)
Flash point :125 °F
storage temp. :Keep in dark place,Inert atmosphere,2-8°C
solubility :31g/l
form :Liquid
pka :2.84(at 25℃)
Specific Gravity :1.617
color :Clear colorless to yellow or slightly brown
Water Solubility :Soluble in water (31 g/L at 20°C).
BRN :105880
Dielectric constant :9.8499999999999996
InChIKey :NYPYPOZNGOXYSU-UHFFFAOYSA-N
LogP :1.694
CAS DataBase Reference :626-55-1(CAS DataBase Reference)
NIST Chemistry Reference :Pyridine, 3-bromo-(626-55-1)
EPA Substance Registry System :3-Bromopyridine (626-55-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

3-Bromopyridine undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, involved in formation of the Grignard by Mg exchange with i-PrMgCl and in transmetallation of the lithiated derivative with zinc chloride followed by treatment with an electrophile as a route to 4-substituted 3-bromopyridines.

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