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3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER

3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER Structure
  • ₹7469.25
  • Product name: 3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER
  • CAS: 33166-79-9
  • MF: C12H14O3
  • MW: 206.24
  • EINECS:
  • MDL Number:MFCD03424816
  • Synonyms:ETHYL 3-OXO-3-M-TOLYLPROPANOATE;ETHYL (3-METHYLBENZOYL)ACETATE;3-OXO-3-M-TOLYL-PROPIONIC ACID ETHYL ESTER;3-OXO-3-(3-TOLYL)PROPIONIC ACID ETHYL ESTER;ETHYL 3-(3-METHYLPHENYL)-3-OXOPROPANOATE;Ethyl 2-(3-methylbenzoyl)acetate;Ethyl 3-oxo-3-(m-tolyl)propionate;Ethyl m-methylbenzoylacetate
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Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number559180
  • Product descriptionEthyl (3-methylbenzoyl)acetate
  • Packaging1G
  • Price₹7469.25
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 559180 Ethyl (3-methylbenzoyl)acetate 1G ₹7469.25 2022-06-14 Buy

Properties

Boiling point :273-274 °C(lit.)
Density :1.083 g/mL at 25 °C(lit.)
refractive index :n20/D 1.5290(lit.)
Flash point :>230 °F
storage temp. :Sealed in dry,Room Temperature
CAS DataBase Reference :33166-79-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

Ethyl (3-methylbenzoyl)acetate is a reactant that has been used for stereoselective ketonization-olefination of indoles by Co/Mn-mediated oxidative cross-coupling of indoles via dioxygen activation. It has also been used in Enantioselective Michael reaction. Another use of it has been in SEGPhos-ruthenium-catalyzed asymmetric hydrogenation.

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