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ChemicalBook > Product Catalogue >Organic Chemistry >Carboxylic acids and derivatives >Carboxylic acid esters and derivatives >Ethyl (3-chlorobenzoyl)acetate

Ethyl (3-chlorobenzoyl)acetate

Ethyl (3-chlorobenzoyl)acetate Structure
  • ₹8724.95 - ₹43083.5
  • Product name: Ethyl (3-chlorobenzoyl)acetate
  • CAS: 33167-21-4
  • MF: C11H11ClO3
  • MW: 226.66
  • EINECS:
  • MDL Number:MFCD03424810
  • Synonyms:ETHYL 3-(3-CHLOROPHENYL)-3-OXOPROPANOATE;ETHYL (3-CHLOROBENZOYL)ACETATE;3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER;Ethyl 2-(3-chlorobenzoyl)acetate;3-Chloro--oxobenzenepropanoic acid ethyl ester;Ethyl (3-chlorobenzoyl)acetate >=97%;3-(3-chlorophenyl)-3-keto-propionic acid ethyl ester;3-(3-chlorophenyl)-3-oxopropanoic acid ethyl ester
Price2 Properties Safety Information Description
2 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)

Package

  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number559288
  • Product descriptionEthyl (3-chlorobenzoyl)acetate ≥97%
  • Packaging1G
  • Price₹8724.95
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number559288
  • Product descriptionEthyl (3-chlorobenzoyl)acetate ≥97%
  • Packaging5G
  • Price₹43083.5
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 559288 Ethyl (3-chlorobenzoyl)acetate ≥97% 1G ₹8724.95 2022-06-14 Buy
Sigma-Aldrich(India) 559288 Ethyl (3-chlorobenzoyl)acetate ≥97% 5G ₹43083.5 2022-06-14 Buy

Properties

Boiling point :257-258 °C (lit.)
Density :1.213 g/mL at 25 °C (lit.)
refractive index :n20/D 1.5460(lit.)
Flash point :>230 °F
storage temp. :Sealed in dry,Room Temperature
pka :9.91±0.46(Predicted)
CAS DataBase Reference :33167-21-4(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

Reagent / reactant involved in:
  • Oxidative cross-coupling via dioxygen activation with indoles
  • Chlorination and hydrosilylation for synthesis of α-hydroxy β-amino acid derivatives
  • Precursor for substrates for chiral Lewis base-catalyzed stereoselective reduction with trichlorosilane and water
  • Intramolecular cyclization for synthesis of dihydrofurans
  • Rate acceleration of Michael reactions
  • Cerium ammonium nitrate-mediated oxidative coupling

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