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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >tert-Butyl(triphenylphosphoranylidene)acetate

tert-Butyl(triphenylphosphoranylidene)acetate

tert-Butyl(triphenylphosphoranylidene)acetate Structure
  • ₹5250.13 - ₹15479.75
  • Product name: tert-Butyl(triphenylphosphoranylidene)acetate
  • CAS: 35000-38-5
  • MF: C24H25O2P
  • MW: 376.43
  • EINECS:412-880-7
  • MDL Number:MFCD00075545
  • Synonyms:(tert-ButoxycarbonylMethylene)triphenylphosphorane, 97% 1GR;(tert-ButoxycarbonylMethylene)triphenylphosphorane, 97% 5GR;(tert-ButoxycarbonylMethylene)triphenylphosphorane 98%;Acetic acid, 2-(triphenylphosphoranylidene)-, 1,1-diMethylethyl ester;LABOTEST-BB LT00233234;(TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)-ACETIC ACID TERT-BUTYL ESTER;(tert-butoxycarbonylmethylene)triphenyl-phosphora;tert-Butyl (triphenylphosphoranylidene)acetate~(Carbo-tert-butoxymethylene)triphenylphosphorane
2 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number369799
  • Product description(tert-Butoxycarbonylmethylene)triphenylphosphorane 98%
  • Packaging5G
  • Price₹5250.13
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number369799
  • Product description(tert-Butoxycarbonylmethylene)triphenylphosphorane 98%
  • Packaging25G
  • Price₹15479.75
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 369799 (tert-Butoxycarbonylmethylene)triphenylphosphorane 98% 5G ₹5250.13 2022-06-14 Buy
Sigma-Aldrich(India) 369799 (tert-Butoxycarbonylmethylene)triphenylphosphorane 98% 25G ₹15479.75 2022-06-14 Buy

Properties

Melting point :152-155 °C(lit.)
Boiling point :503.5±33.0 °C(Predicted)
Density :1.203(20.0000℃)
storage temp. :2-8°C
solubility :Chloroform (Slightly), Ethyl Acetate (Slightly)
form :Crystalline Powder
color :White
Water Solubility :Sparingly soluble in water.
BRN :2759875
InChI :InChI=1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
InChIKey :ZWZUFQPXYVYAFO-UHFFFAOYSA-N
SMILES :C(OC(C)(C)C)(=O)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference :35000-38-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314 Get medical advice/attention if you feel unwell.

Description

(tert-Butoxycarbonylmethylene)triphenylphosphorane is a chemical used in the synthesis of aldose reductase inhibitors, a podophyllotoxin derivative and tautomycin, a podophyllotoxin derivative and tautomycin. It Is also used in medicinal chemistry.

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