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ChemicalBook > Product Catalogue >Organic Chemistry >Inorganic acid Esters >1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Structure
  • ₹1905 - ₹22700
  • Product name: 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
  • CAS: 35193-63-6
  • MF: C20H13O4P
  • MW: 348.29
  • EINECS:252-425-8
  • MDL Number:MFCD00010045
  • Synonyms:(+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE;1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE;(+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE;2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE;4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;(R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE;(R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID;(R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1g
  • 5g
  • 25G
  • ManufacturerALFA India
  • Product numberALF-H60395-03
  • Product description1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%
  • Packaging1g
  • Price₹1905
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H60395-06
  • Product description1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%
  • Packaging5g
  • Price₹8770
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2130
  • Product description(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
  • Packaging5G
  • Price₹6400
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2130
  • Product description(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
  • Packaging25G
  • Price₹22700
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number292966
  • Product description1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 95%
  • Packaging5G
  • Price₹7285.23
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-H60395-03 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99% 1g ₹1905 2022-05-26 Buy
ALFA India ALF-H60395-06 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99% 5g ₹8770 2022-05-26 Buy
TCI Chemicals (India) B2130 (±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate 5G ₹6400 2022-05-26 Buy
TCI Chemicals (India) B2130 (±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate 25G ₹22700 2022-05-26 Buy
Sigma-Aldrich(India) 292966 1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 95% 5G ₹7285.23 2022-06-14 Buy

Properties

Melting point :≥300 °C
Boiling point :619.5±38.0 °C(Predicted)
Density :1.49±0.1 g/cm3(Predicted)
storage temp. :Sealed in dry,Room Temperature
form :Solid
pka :1.14±0.20(Predicted)
color :White to Yellow to Orange
Water Solubility :Extremely low soluble in water.
CAS DataBase Reference :35193-63-6(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

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