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2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Structure
  • ₹12930 - ₹61580
  • Product name: 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
  • CAS: 357209-32-6
  • MF: C25H19N3O2
  • MW: 393.44
  • EINECS:
  • MDL Number:MFCD09265074
  • Synonyms:2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&;2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE;(3aR,8aS)-in-pybox, (3aR,3μaR,8aS,8μaS)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;8H-Indeno[1,2-d]oxazole,2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-;(3aR,3'aR,8aS,8'aS)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%
2 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • ManufacturerSigma-Aldrich(India)
  • Product number673986
  • Product description2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine ≥94%
  • Packaging1G
  • Price₹61580
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number673986
  • Product description2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine ≥94%
  • Packaging250MG
  • Price₹12930
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 673986 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine ≥94% 1G ₹61580 2022-06-14 Buy
Sigma-Aldrich(India) 673986 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine ≥94% 250MG ₹12930 2022-06-14 Buy

Properties

Melting point :284 °C (dec.)
Boiling point :633.0±55.0 °C(Predicted)
Density :1.50±0.1 g/cm3(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
pka :4.35±0.20(Predicted)
optical activity :[α]20/D +386°, c = 1 in methylene chloride(lit.)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Catalytic ligand used for:
  • [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
  • Enantioselective Mukaiyama-aldol reactions
  • Enantioselective carbonyl-ene reactions
  • Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
  • Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
  • Enantioselective Diels-Alder reaction
  • Ni-catalyzed cross-coupling reactions

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