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9-METHOXY-9-BORABICYCLO[3.3.1]NONANE

9-METHOXY-9-BORABICYCLO[3.3.1]NONANE Structure
  • ₹5426.4
  • Product name: 9-METHOXY-9-BORABICYCLO[3.3.1]NONANE
  • CAS: 38050-71-4
  • MF: C9H17BO
  • MW: 152.04
  • EINECS:253-758-1
  • MDL Number:MFCD00006687
  • Synonyms:9-Borabicyclo[3.3.1]nonane,9-methoxy- ;9-METHOXY-9-BORABICYCLO[3.3.1]NONANE;B-METHOXY-9-BBN, 1.0M SOLUTION IN HEXANE S;b-methoxy-9-bbn solution;8-Methoxy-9-borabicyclo[3,3,1]nonane;9- methoxy-9-borabicyclo[3.3.1]nonane 1.0M in hexanes;B-Methoxy-9-BBN solution,9-Methoxy-9-borabicyclo[3.3.1]nonane;B-Methoxy-9-borabicyclo[3.3.1]nonane
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Brand

  • Sigma-Aldrich(India)

Package

  • 100ML
  • ManufacturerSigma-Aldrich(India)
  • Product number196223
  • Product descriptionB-Methoxy-9-BBN solution 1.0?M in hexanes
  • Packaging100ML
  • Price₹5426.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 196223 B-Methoxy-9-BBN solution 1.0?M in hexanes 100ML ₹5426.4 2022-06-14 Buy

Properties

Boiling point :57-58 °C(Press: 7 Torr)
Density :0.716 g/mL at 25 °C
Flash point :−9 °F
InChI :InChI=1S/C9H17BO/c1-11-10-8-4-2-5-9(10)7-3-6-8/h8-9H,2-7H2,1H3
InChIKey :UNGDGQYONLTNJZ-UHFFFAOYSA-N
SMILES :C12B(OC)C(CCC1)CCC2

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P281 Use personal protective equipment as required.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331 Do NOT induce vomiting.

Description

B-Methoxy-9-BBN solution is a co-catalyst and nucleophile promoter for indium-catalyzed allylation reactions of methyl ethers and carbohydrate derivatives. B-Methoxy-9-BBN solution also acts as a catalyst for linear allene formation and as a synthetic reagent for Suzuki reactions.

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