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ChemicalBook > Product Catalogue >Organic Chemistry >Hydrocarbons and derivatives >Hydrocarbon nitrification >4-NITROCINNAMALDEHYDE

4-NITROCINNAMALDEHYDE

4-NITROCINNAMALDEHYDE Structure
  • ₹17071.03
  • Product name: 4-NITROCINNAMALDEHYDE
  • CAS: 1734-79-8
  • MF: C9H7NO3
  • MW: 177.16
  • EINECS:217-076-8
  • MDL Number:MFCD00007379
  • Synonyms:4-NITROCINNAMALDEHYDE;3-(4-NITROPHENYL)-2-PROPENAL;PARA-NITROCINNAMALDEHYDE;p-Nitrocinnamaldehyde,98%;4-Nitrobenzeneacrylaldehyde;4-Nitrobenzenepropenal;3-(4-Nitrophenyl)acrylaldehyde 3-(4-Nitrophenyl)-2-propenal;3-(4-Nitrophenyl)acrylaldehyde
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Brand

  • Sigma-Aldrich(India)

Package

  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number74115
  • Product descriptiontrans-4-Nitrocinnamaldehyde technical, ≥97.0% (T)
  • Packaging5G
  • Price₹17071.03
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 74115 trans-4-Nitrocinnamaldehyde technical, ≥97.0% (T) 5G ₹17071.03 2022-06-14 Buy

Properties

Melting point :140-143 °C(lit.)
Boiling point :309.06°C (rough estimate)
Density :1.3312 (rough estimate)
refractive index :1.5200 (estimate)
storage temp. :Inert atmosphere,Store in freezer, under -20°C
Water Solubility :Insoluble in water.
Sensitive :Air Sensitive
BRN :1565424
CAS DataBase Reference :1734-79-8(CAS DataBase Reference)
EPA Substance Registry System :2-Propenal, 3-(4-nitrophenyl)- (1734-79-8)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.

Description

Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

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