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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Esters >Methyl ester compound >Methyl 4-methoxyacetoacetate

Methyl 4-methoxyacetoacetate

Methyl 4-methoxyacetoacetate Structure
  • ₹3900 - ₹18260
  • Product name: Methyl 4-methoxyacetoacetate
  • CAS: 41051-15-4
  • MF: C6H10O4
  • MW: 146.14
  • EINECS:255-188-9
  • MDL Number:MFCD00010183
  • Synonyms:4-methoxy-3-oxo-butanoicacimethylester ;Butanoic acid, 4-methoxy-3-oxo-, methyl ester;Methyl methoxyacetoacetate;4-METHOXYACETOACETIC ACID METHYL ESTER;METHYL 4-METHOXYACETOACETATE;METHYL 4-METHOXYACETOXYACETATE;METHYL 4-METHOXY-3-OXO-BUTANOATE;3-Oxo-4-methoxybutanoic acid methyl ester
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberM1031
  • Product descriptionMethyl 4-Methoxyacetoacetate min. 97.0 %
  • Packaging5G
  • Price₹3900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberM1031
  • Product descriptionMethyl 4-Methoxyacetoacetate min. 97.0 %
  • Packaging25G
  • Price₹10000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number281506
  • Product descriptionMethyl 4-methoxyacetoacetate 97%
  • Packaging5G
  • Price₹6150
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number281506
  • Product descriptionMethyl 4-methoxyacetoacetate 97%
  • Packaging25G
  • Price₹18260
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) M1031 Methyl 4-Methoxyacetoacetate min. 97.0 % 5G ₹3900 2022-05-26 Buy
TCI Chemicals (India) M1031 Methyl 4-Methoxyacetoacetate min. 97.0 % 25G ₹10000 2022-05-26 Buy
Sigma-Aldrich(India) 281506 Methyl 4-methoxyacetoacetate 97% 5G ₹6150 2022-06-14 Buy
Sigma-Aldrich(India) 281506 Methyl 4-methoxyacetoacetate 97% 25G ₹18260 2022-06-14 Buy

Properties

Melting point :-80℃
Boiling point :89 °C/8.5 mmHg (lit.)
Density :1.129 g/mL at 25 °C (lit.)
refractive index :n20/D 1.431(lit.)
Flash point :193 °F
storage temp. :Sealed in dry,Room Temperature
form :clear liquid
pka :9.88±0.46(Predicted)
Specific Gravity :1.129
color :Colorless to Light yellow to Light orange
BRN :1761215
InChIKey :QGBPKJFJAVDUNC-UHFFFAOYSA-N
LogP :0.340 (est)
CAS DataBase Reference :41051-15-4(CAS DataBase Reference)
NIST Chemistry Reference :Methyl 4-methoxyacetoacetate(41051-15-4)
EPA Substance Registry System :Methyl 4-methoxyacetoacetate (41051-15-4)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl 4-methoxyacetoacetate has been used in generation of a small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and (thio)ureas.

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