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ChemicalBook > Product Catalogue >Organic Chemistry >Amides >Naphthenic amines derivatives >1,1'-Binaphthyl-2,2'-diamine

1,1'-Binaphthyl-2,2'-diamine

1,1'-Binaphthyl-2,2'-diamine Structure
  • ₹4518 - ₹34804
  • Product name: 1,1'-Binaphthyl-2,2'-diamine
  • CAS: 4488-22-6
  • MF: C20H16N2
  • MW: 284.35
  • EINECS:
  • MDL Number:MFCD00145204
  • Synonyms:(+/-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE;(+/-)-2,2'-DIAMINO-1,1'-BINAPHTHALENE;2,2-DIAMINO-1,1'-BINAPHTHALENE;RACEMIC-2,2'-DIAMINO-1,1'-BINAPHTHYL, MIN. 96%;1,1-BINAPHY1-2,2'-DIAMINE;(+/-)-2,2'-Diamino-1,1'-binaphthyl;racemic-2,2'-Diamino-1,1'-binaphthyl,min.96%;1-(1-Naphtyl)naphthalen-2-amine
4 prices
Selected condition:

Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1g
  • 5g
  • ManufacturerALFA India
  • Product numberALF-H31264-03
  • Product description(±)-1,1'-Bi(2-naphthylamine), 97%
  • Packaging1g
  • Price₹4518
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H31264-06
  • Product description(±)-1,1'-Bi(2-naphthylamine), 97%
  • Packaging5g
  • Price₹34804
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB3923
  • Product description1,1'-Binaphthyl-2,2'-diamine
  • Packaging1G
  • Price₹5400
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number631698
  • Product description1,1′-Binaphthyl-2,2′-diamine 96%
  • Packaging1G
  • Price₹9160
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-H31264-03 (±)-1,1'-Bi(2-naphthylamine), 97% 1g ₹4518 2022-05-26 Buy
ALFA India ALF-H31264-06 (±)-1,1'-Bi(2-naphthylamine), 97% 5g ₹34804 2022-05-26 Buy
TCI Chemicals (India) B3923 1,1'-Binaphthyl-2,2'-diamine 1G ₹5400 2022-05-26 Buy
Sigma-Aldrich(India) 631698 1,1′-Binaphthyl-2,2′-diamine 96% 1G ₹9160 2022-06-14 Buy

Properties

Melting point :242-244 °C(lit.)
Boiling point :416.85°C (rough estimate)
Density :1.249
refractive index :1.6450 (estimate)
storage temp. :Keep in dark place,Sealed in dry,Room Temperature
pka :3.79±0.10(Predicted)
form :powder to crystal
color :slightly beige
Water Solubility :Insoluble in water
λmax :355nm(neat)(lit.)
InChIKey :DDAPSNKEOHDLKB-UHFFFAOYSA-N

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
Precautionary statements:
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Description

Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1?-binaphthalenyl-2,2?-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities.

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