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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >1.1'-Binaphthyl-2.2'-diphemyl phosphine

1.1'-Binaphthyl-2.2'-diphemyl phosphine

1.1'-Binaphthyl-2.2'-diphemyl phosphine Structure
  • ₹5231 - ₹232369.45
  • Product name: 1.1'-Binaphthyl-2.2'-diphemyl phosphine
  • CAS: 98327-87-8
  • MF: C44H32P2
  • MW: 622.69
  • EINECS:619-338-0
  • MDL Number:MFCD00010805
  • Synonyms:(+/-)-(1,1'-BINAPHTHALENE-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE);(+/-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL;2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL;(+/-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENE;Racemic-2,2’-bis(diphenylphosphino)-1,1’-binaphthy;RACEMIC-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL BINAP;RAC-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL / RAC-BINAP;2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl (Racemic BINAP)
9 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 5G
  • 25G
  • 100G
  • 500G
  • ManufacturerTCI Chemicals (India)
  • Product numberB2383
  • Product description(±)-BINAP min. 97.0 %
  • Packaging5G
  • Price₹6700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2383
  • Product description(±)-BINAP min. 97.0 %
  • Packaging25G
  • Price₹24600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number481084
  • Product descriptionrac-BINAP 97%
  • Packaging5G
  • Price₹13350
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number481084
  • Product descriptionrac-BINAP 97%
  • Packaging25G
  • Price₹23187.15
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number481084
  • Product descriptionrac-BINAP 97%
  • Packaging100G
  • Price₹68078.43
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number481084
  • Product descriptionrac-BINAP 97%
  • Packaging500G
  • Price₹232369.45
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H26226-22
  • Product description(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+%
  • Packaging100g
  • Price₹65417
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H26226-14
  • Product description(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+%
  • Packaging25g
  • Price₹18828
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H26226-06
  • Product description(+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+%
  • Packaging5g
  • Price₹5231
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B2383 (±)-BINAP min. 97.0 % 5G ₹6700 2022-05-26 Buy
TCI Chemicals (India) B2383 (±)-BINAP min. 97.0 % 25G ₹24600 2022-05-26 Buy
Sigma-Aldrich(India) 481084 rac-BINAP 97% 5G ₹13350 2022-06-14 Buy
Sigma-Aldrich(India) 481084 rac-BINAP 97% 25G ₹23187.15 2022-06-14 Buy
Sigma-Aldrich(India) 481084 rac-BINAP 97% 100G ₹68078.43 2022-06-14 Buy
Sigma-Aldrich(India) 481084 rac-BINAP 97% 500G ₹232369.45 2022-06-14 Buy
ALFA India ALF-H26226-22 (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+% 100g ₹65417 2022-05-26 Buy
ALFA India ALF-H26226-14 (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+% 25g ₹18828 2022-05-26 Buy
ALFA India ALF-H26226-06 (+/-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97+% 5g ₹5231 2022-05-26 Buy

Properties

Melting point :283-286 °C(lit.)
Boiling point :724.3±55.0 °C(Predicted)
storage temp. :Keep in dark place,Inert atmosphere,Room temperature
solubility :Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),
form :Powder
color :White to light beige
Water Solubility :Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.
Sensitive :Air Sensitive
Merck :14,1223
BRN :5321443
InChIKey :MUALRAIOVNYAIW-UHFFFAOYSA-N
CAS DataBase Reference :98327-87-8(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

(^+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl plays an essential role in the organic synthesis of enantioselective transformations catalyzed by the complexes of ruthenium, rhodium and palladium. It is also employed in palladium-catalyzed arylamine coupling in the preparation of demethylthiocholchines. It is used with Cu(II) to catalyze the addition of arylsulfonamides to styrenes and olefins.

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