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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Structure
  • ₹1494 - ₹49509
  • Product name: (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
  • CAS: 76189-56-5
  • MF: C44H32P2
  • MW: 622.69
  • EINECS:616-305-2
  • MDL Number:MFCD00010805
  • Synonyms:(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene puriss.;(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-biphthyl;(S)-BINAP,99%e.e.;(S)-(-)-2,2'-Bis(diphenylphoshino)-1,1'-binaphthyl for synthesis;2-(diphenylphosphino)-1-(2-(diphenylphosphino)naphthalen-1-yl)naphthalene;(+/-)-BINAP;(+/-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENE;S(-)-(1,1'-BINAPHTHALENE-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE)
12 prices
Selected condition:

Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ottokemi

Package

  • 100MG
  • 250MG
  • 500MG
  • 1gm
  • 1G
  • 5G
  • 5gm
  • 25gm
  • 1ea
  • ManufacturerALFA India
  • Product numberALF-B23872-MD
  • Product description(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97%
  • Packaging1ea
  • Price₹1810
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1405
  • Product description(S)-(-)-BINAP
  • Packaging1G
  • Price₹5900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1405
  • Product description(S)-(-)-BINAP
  • Packaging5G
  • Price₹14600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number693057
  • Product description(S)-BINAP
  • Packaging100MG
  • Price₹2598
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number295825
  • Product description(S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 97%
  • Packaging250MG
  • Price₹2792.85
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number295825
  • Product description(S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 97%
  • Packaging1G
  • Price₹7047.08
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number693057
  • Product description(S)-BINAP
  • Packaging500MG
  • Price₹8227
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number295825
  • Product description(S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 97%
  • Packaging5G
  • Price₹34315.25
  • Updated2022-06-14
  • Buy
  • Manufacturerottokemi
  • Product number B 1806
  • Product descriptionS-BINAP
  • Packaging250mg
  • Price₹1494
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1806
  • Product descriptionS-BINAP
  • Packaging1gm
  • Price₹4959
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1806
  • Product descriptionS-BINAP
  • Packaging5gm
  • Price₹15903
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1806
  • Product descriptionS-BINAP
  • Packaging25gm
  • Price₹49509
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-B23872-MD (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl, 97% 1ea ₹1810 2022-05-26 Buy
TCI Chemicals (India) B1405 (S)-(-)-BINAP 1G ₹5900 2022-05-26 Buy
TCI Chemicals (India) B1405 (S)-(-)-BINAP 5G ₹14600 2022-05-26 Buy
Sigma-Aldrich(India) 693057 (S)-BINAP 100MG ₹2598 2022-06-14 Buy
Sigma-Aldrich(India) 295825 (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 97% 250MG ₹2792.85 2022-06-14 Buy
Sigma-Aldrich(India) 295825 (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 97% 1G ₹7047.08 2022-06-14 Buy
Sigma-Aldrich(India) 693057 (S)-BINAP 500MG ₹8227 2022-06-14 Buy
Sigma-Aldrich(India) 295825 (S)-(−)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene 97% 5G ₹34315.25 2022-06-14 Buy
ottokemi B 1806 S-BINAP 250mg ₹1494 2022-05-26 Buy
ottokemi B 1806 S-BINAP 1gm ₹4959 2022-05-26 Buy
ottokemi B 1806 S-BINAP 5gm ₹15903 2022-05-26 Buy
ottokemi B 1806 S-BINAP 25gm ₹49509 2022-05-26 Buy

Properties

Melting point :283-286 °C(lit.)
alpha :-240 º (c=0.3, toluene)
Boiling point :724.3±55.0 °C(Predicted)
refractive index :-235 ° (C=0.3, Toluene)
storage temp. :Inert atmosphere,Room Temperature
solubility :Benzene (Slightly), Chloroform (Slightly)
form :Crystals or Crystalline Powder
color :White to light yellow
optical activity :[α]20/D -222, c = 0.5 in benzene
Sensitive :Air Sensitive
Merck :14,1223
BRN :5321444
CAS DataBase Reference :76189-56-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

As a chiral ligand for asymmetric transition metal based catalyst production

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