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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Diphenylphosphine

Diphenylphosphine

Diphenylphosphine Structure
  • ₹130995
  • Product name: Diphenylphosphine
  • CAS: 829-85-6
  • MF: C12H11P
  • MW: 186.19
  • EINECS:212-591-4
  • MDL Number:MFCD00003040
  • Synonyms:PHOSPHINE, DIPHENYL;Diphenyl-phosphane ;Diphenyl phospine;Diphenylphosphine,99%;Diphenylphosphine,99%(10wt%inhexane);DIPHENYLPHOSPHINE;AURORA KA-1107;DIPHENYLPHOSPHINE OR PHOSPHINE, DIPHENYL
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Brand

  • ottokemi

Package

  • 50gm
  • Manufacturerottokemi
  • Product number D 8307
  • Product descriptionDiphenylphosphine
  • Packaging50gm
  • Price₹130995
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ottokemi D 8307 Diphenylphosphine 50gm ₹130995 2022-05-26 Buy

Properties

Melting point :-14.5 °C
Boiling point :280 °C(lit.)
Density :1.07 g/mL at 25 °C(lit.)
vapor pressure :2 mm Hg ( 110 °C)
refractive index :n20/D 1.625(lit.)
Flash point :-18°C (Hexane)
storage temp. :2-8°C
solubility :Chloroform
form :liquid
pka :diphenylphosphine is weakly basic. The pKa of the protonated derivative is 0.03.
color :colorless
Specific Gravity :0.68
Water Solubility :Miscible with ethanol, ether, benzene, concentrated hydrochloric acid. Immiscible with water.
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :742504
InChIKey :GPAYUJZHTULNBE-UHFFFAOYSA-N
CAS DataBase Reference :829-85-6(CAS DataBase Reference)
NIST Chemistry Reference :Phosphine, diphenyl-(829-85-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P231+P232 Handle under inert gas. Protect from moisture.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Diphenylphosphine acts as an intermediate in the preparation of diphenylphosphide derivatives, phosphonium salts, phosphine ligands and Wittig-Horner reagents. The presence of hydrogen atom bonded to phosphorus undergoes Michael-like addition to activated alkenes. It is involved in the preparation of 1,2-bis(diphenylphosphino)ethane and (phenyl-(phenylmethyl)phosphoryl)benzene. Further, it is used in the synthesis of aminophosphines and chiral palladacycles with N-heterocyclic carbene ligands as catalysts.

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