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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic iron >1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene Structure
  • ₹846 - ₹44600
  • Product name: 1,1'-Bis(diphenylphosphino)ferrocene
  • CAS: 12150-46-8
  • MF: C34H28FeP210*
  • MW: 554.38
  • EINECS:640-119-0
  • MDL Number:MFCD00001422
  • Synonyms:1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE;1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF);DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE;1,1'-Bis(diphenylphosphiNA)ferrocene;DPPF, (Ferrocene-1,1'-diyl)bis(diphenylphosphine);1,1-(twophenylphosphine)Er Maotie;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE)
12 prices
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • SRL
  • ottokemi

Package

  • 1gm
  • 1G
  • 5gm
  • 5G
  • 10G
  • 25G
  • 25gm
  • 1Gms
  • 5Gms
  • 25Gms
  • ManufacturerTCI Chemicals (India)
  • Product numberB2027
  • Product description1,1'-Bis(diphenylphosphino)ferrocene
  • Packaging1G
  • Price₹2900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2027
  • Product description1,1'-Bis(diphenylphosphino)ferrocene
  • Packaging5G
  • Price₹6100
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2027
  • Product description1,1'-Bis(diphenylphosphino)ferrocene
  • Packaging25G
  • Price₹13900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number177261
  • Product descriptionDPPF 97%
  • Packaging1G
  • Price₹2850
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number177261
  • Product descriptionDPPF 97%
  • Packaging10G
  • Price₹17290
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number177261
  • Product descriptionDPPF 97%
  • Packaging25G
  • Price₹44600
  • Updated2022-06-14
  • Buy
  • ManufacturerSRL
  • Product number23660
  • Product descriptionDPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%
  • Packaging25Gms
  • Price₹12270
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number23660
  • Product descriptionDPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%
  • Packaging5Gms
  • Price₹3600
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number23660
  • Product descriptionDPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%
  • Packaging1Gms
  • Price₹960
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 0490
  • Product descriptionDPPF 97%
  • Packaging1gm
  • Price₹846
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 0490
  • Product descriptionDPPF 97%
  • Packaging5gm
  • Price₹3249
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number D 0490
  • Product descriptionDPPF 97%
  • Packaging25gm
  • Price₹13959
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B2027 1,1'-Bis(diphenylphosphino)ferrocene 1G ₹2900 2022-05-26 Buy
TCI Chemicals (India) B2027 1,1'-Bis(diphenylphosphino)ferrocene 5G ₹6100 2022-05-26 Buy
TCI Chemicals (India) B2027 1,1'-Bis(diphenylphosphino)ferrocene 25G ₹13900 2022-05-26 Buy
Sigma-Aldrich(India) 177261 DPPF 97% 1G ₹2850 2022-06-14 Buy
Sigma-Aldrich(India) 177261 DPPF 97% 10G ₹17290 2022-06-14 Buy
Sigma-Aldrich(India) 177261 DPPF 97% 25G ₹44600 2022-06-14 Buy
SRL 23660 DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98% 25Gms ₹12270 2022-05-26 Buy
SRL 23660 DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98% 5Gms ₹3600 2022-05-26 Buy
SRL 23660 DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98% 1Gms ₹960 2022-05-26 Buy
ottokemi D 0490 DPPF 97% 1gm ₹846 2022-05-26 Buy
ottokemi D 0490 DPPF 97% 5gm ₹3249 2022-05-26 Buy
ottokemi D 0490 DPPF 97% 25gm ₹13959 2022-05-26 Buy

Properties

Melting point :181-182 °C (dec.)(lit.)
storage temp. :2-8°C
solubility :Chloroform, Ethyl Acetate
form :crystal
color :yellow to orange
Water Solubility :Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive :Air Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Stability :Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference :12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference :1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

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