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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Structure
  • ₹2500 - ₹21758.25
  • Product name: 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
  • CAS: 14647-23-5
  • MF: C26H24Cl2NiP2
  • MW: 528.02
  • EINECS:629-489-4
  • MDL Number:MFCD00013313
  • Synonyms:DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II);1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE;1,2-Bis(diphenylphosphino)ethane nickel(II) chloride,98%;Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel;1.2-Bis(dipheny phosphine) ethane nickel(II)chloride
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 1G
  • 2g
  • 5G
  • 10g
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberB2225
  • Product description[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
  • Packaging1G
  • Price₹2500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2225
  • Product description[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
  • Packaging5G
  • Price₹7000
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB2225
  • Product description[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
  • Packaging25G
  • Price₹16800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number328219
  • Product description[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
  • Packaging1G
  • Price₹3128.43
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number328219
  • Product description[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
  • Packaging5G
  • Price₹9883.23
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number328219
  • Product description[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
  • Packaging25G
  • Price₹21758.25
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-013932-09
  • Product descriptionDichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%
  • Packaging10g
  • Price₹12033
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-013932-04
  • Product descriptionDichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%
  • Packaging2g
  • Price₹4807
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B2225 [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride 1G ₹2500 2022-05-26 Buy
TCI Chemicals (India) B2225 [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride 5G ₹7000 2022-05-26 Buy
TCI Chemicals (India) B2225 [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride 25G ₹16800 2022-05-26 Buy
Sigma-Aldrich(India) 328219 [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) 1G ₹3128.43 2022-06-14 Buy
Sigma-Aldrich(India) 328219 [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) 5G ₹9883.23 2022-06-14 Buy
Sigma-Aldrich(India) 328219 [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) 25G ₹21758.25 2022-06-14 Buy
ALFA India ALF-013932-09 Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98% 10g ₹12033 2022-05-26 Buy
ALFA India ALF-013932-04 Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98% 2g ₹4807 2022-05-26 Buy

Properties

Melting point :263-265 °C(lit.)
storage temp. :Inert atmosphere,2-8°C
solubility :Chloroform, Methanol (Sparingly)
form :crystal
color :orange
Water Solubility :insoluble
Exposure limits :NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability :Hygroscopic
CAS DataBase Reference :14647-23-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger GHS hazard pictograms P261, P285, P304+P341, P342+P311,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
Precautionary statements:
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

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