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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane Structure
  • ₹423 - ₹13444.65
  • Product name: 1,3-Bis(diphenylphosphino)propane
  • CAS: 6737-42-4
  • MF: C27H26P2
  • MW: 412.45
  • EINECS:229-791-2
  • MDL Number:MFCD00003050
  • Synonyms:1,3-BIS(DIPHENYLPHOSPHINO)PROPANE;TRIMETHYLENEBIS(DIPHENYLPHOSPHINE);[3-(Diphenylphosphino)propyl](diphenyl)phosphine;1,3-Propanediylbis(diphenylphosphine);Phosphine, 1,3-propanediylbis[diphenyl-;Phosphine, trimethylenebis(diphenyl-;Propane-1,3-diylbis(diphenylphosphine);PROPYLENEBIS(DIPHENYLPHOSPHINE)
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • SRL
  • ottokemi

Package

  • 100mg
  • 1gm
  • 1G
  • 5G
  • 5gm
  • 25G
  • 25gm
  • 1Gms
  • 5Gms
  • 25Gms
  • ManufacturerTCI Chemicals (India)
  • Product numberB1138
  • Product description1,3-Bis(diphenylphosphino)propane min. 98.0 %
  • Packaging5G
  • Price₹4200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1138
  • Product description1,3-Bis(diphenylphosphino)propane min. 98.0 %
  • Packaging25G
  • Price₹7900
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number262048
  • Product description1,3-Bis(diphenylphosphino)propane 97%
  • Packaging1G
  • Price₹1948.5
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number262048
  • Product description1,3-Bis(diphenylphosphino)propane 97%
  • Packaging5G
  • Price₹4957.85
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number262048
  • Product description1,3-Bis(diphenylphosphino)propane 97%
  • Packaging25G
  • Price₹13444.65
  • Updated2022-06-14
  • Buy
  • ManufacturerSRL
  • Product number34103
  • Product descriptionDPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98%
  • Packaging1Gms
  • Price₹720
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number34103
  • Product descriptionDPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98%
  • Packaging5Gms
  • Price₹2140
  • Updated2022-05-26
  • Buy
  • ManufacturerSRL
  • Product number34103
  • Product descriptionDPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98%
  • Packaging25Gms
  • Price₹9490
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1807
  • Product description1,3-Bis(diphenylphosphino) propane 97%
  • Packaging100mg
  • Price₹423
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1807
  • Product description1,3-Bis(diphenylphosphino) propane 97%
  • Packaging1gm
  • Price₹1818
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1807
  • Product description1,3-Bis(diphenylphosphino) propane 97%
  • Packaging5gm
  • Price₹4608
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number B 1807
  • Product description1,3-Bis(diphenylphosphino) propane 97%
  • Packaging25gm
  • Price₹12402
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B1138 1,3-Bis(diphenylphosphino)propane min. 98.0 % 5G ₹4200 2022-05-26 Buy
TCI Chemicals (India) B1138 1,3-Bis(diphenylphosphino)propane min. 98.0 % 25G ₹7900 2022-05-26 Buy
Sigma-Aldrich(India) 262048 1,3-Bis(diphenylphosphino)propane 97% 1G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 262048 1,3-Bis(diphenylphosphino)propane 97% 5G ₹4957.85 2022-06-14 Buy
Sigma-Aldrich(India) 262048 1,3-Bis(diphenylphosphino)propane 97% 25G ₹13444.65 2022-06-14 Buy
SRL 34103 DPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98% 1Gms ₹720 2022-05-26 Buy
SRL 34103 DPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98% 5Gms ₹2140 2022-05-26 Buy
SRL 34103 DPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98% 25Gms ₹9490 2022-05-26 Buy
ottokemi B 1807 1,3-Bis(diphenylphosphino) propane 97% 100mg ₹423 2022-05-26 Buy
ottokemi B 1807 1,3-Bis(diphenylphosphino) propane 97% 1gm ₹1818 2022-05-26 Buy
ottokemi B 1807 1,3-Bis(diphenylphosphino) propane 97% 5gm ₹4608 2022-05-26 Buy
ottokemi B 1807 1,3-Bis(diphenylphosphino) propane 97% 25gm ₹12402 2022-05-26 Buy

Properties

Melting point :63-65 °C (lit.)
Boiling point :529.7±33.0 °C(Predicted)
Flash point :235°C
storage temp. :Inert atmosphere,Room Temperature
form :Granules or Powder
color :White to light yellow-beige
Water Solubility :insoluble
Sensitive :Air Sensitive
BRN :2821785
InChI :InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey :LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES :P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference :6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference :1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System :Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

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