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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organonickel >[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Structure
  • ₹2449 - ₹27322.3
  • Product name: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
  • CAS: 15629-92-2
  • MF: C27H26Cl2NiP2
  • MW: 542.04
  • EINECS:605-052-3
  • MDL Number:MFCD00015318
  • Synonyms:NiCl2(DPPP)NiCl2(DPPP);1.3-Bis(dipheny phosphine) propane nickel(II)chloride;DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE;NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE;1,3-Bis-(diphenylphosphino)-propane nickel chloride;Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%;(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride;Dichloro1,3-Bis-(diphenylphosphino ) propane nickel (II)（DPPE.Nicl2） 98%
Price6 Properties Safety Information Description
6 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)
  • ALFA India
  • TCI Chemicals (India)

Package

  • 2g
  • 5G
  • 10g
  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number335363
  • Product description[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
  • Packaging25G
  • Price₹27322.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number335363
  • Product description[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
  • Packaging5G
  • Price₹12567.83
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-030167-09
  • Product descriptionDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)
  • Packaging10g
  • Price₹9933
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-030167-04
  • Product descriptionDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)
  • Packaging2g
  • Price₹2449
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1313
  • Product description[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
  • Packaging25G
  • Price₹20800
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB1313
  • Product description[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
  • Packaging5G
  • Price₹6300
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 335363 [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) 25G ₹27322.3 2022-06-14 Buy
Sigma-Aldrich(India) 335363 [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) 5G ₹12567.83 2022-06-14 Buy
ALFA India ALF-030167-09 Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) 10g ₹9933 2022-05-26 Buy
ALFA India ALF-030167-04 Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) 2g ₹2449 2022-05-26 Buy
TCI Chemicals (India) B1313 [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride 25G ₹20800 2022-05-26 Buy
TCI Chemicals (India) B1313 [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride 5G ₹6300 2022-05-26 Buy

Properties

Melting point :213 °C (dec.)(lit.)
storage temp. :Inert atmosphere,Room Temperature
form :crystal
color :red
Water Solubility :insoluble
Hydrolytic Sensitivity :4: no reaction with water under neutral conditions
Exposure limits :NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
InChIKey :ZBQUMMFUJLOTQC-UHFFFAOYSA-L
CAS DataBase Reference :15629-92-2(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger GHS hazard pictograms P261, P285, P304+P341, P342+P311,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger GHS hazard pictograms
Precautionary statements:
P201 Obtain special instructions before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.

Description

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

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Suppliers and manufacturers

Omkar Lab MANVI BIOPHARMA PVT LTD, TCI Chemicals (India) Pvt. Ltd. Alfa Aesar Mehta Enterprise A.J Chemicals Reax Chemicals
Puyang Huicheng Electronic Materials Co., Ltd.
Capot Chemical Co.,Ltd.
Shanghai Daken Advanced Materials Co.,Ltd