Phosphine
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Properties
Melting point :-133°
Boiling point :−87.5 °C(lit.)
Density :0.491 (estimate)
vapor density :1.15 (vs air)
vapor pressure :3905kPa at 25℃
solubility :insoluble in H2O; slightly soluble in ethanol, ethyl ether
form :colorless gas
color :colorless gas; flammable
Water Solubility :0.26 volumes in H2O (20°C); insoluble hot H2O; slightly soluble alcohol, ether, cuprous chloride solutions [HAW93] [MER06]
Merck :13,7424
Exposure limits :TLV-TWA 0.42 mg/m3 (0.3 ppm) (ACGIH and OSHA); STEL 1.4 mg/m3 (1 ppm) (ACGIH); IDLH 200 ppm (NIOSH).
Dielectric constant :2.5(-60℃)
Stability :Stable, but pyrophoric - spontaneously flammable in air. Note the very wide explosion limits. Incompatible with oxidizing agents, halogens, nitric acid.
CAS DataBase Reference :7803-51-2(CAS DataBase Reference)
NIST Chemistry Reference :Phosphine(7803-51-2)
EPA Substance Registry System :Phosphine (7803-51-2)
Boiling point :−87.5 °C(lit.)
Density :0.491 (estimate)
vapor density :1.15 (vs air)
vapor pressure :3905kPa at 25℃
solubility :insoluble in H2O; slightly soluble in ethanol, ethyl ether
form :colorless gas
color :colorless gas; flammable
Water Solubility :0.26 volumes in H2O (20°C); insoluble hot H2O; slightly soluble alcohol, ether, cuprous chloride solutions [HAW93] [MER06]
Merck :13,7424
Exposure limits :TLV-TWA 0.42 mg/m3 (0.3 ppm) (ACGIH and OSHA); STEL 1.4 mg/m3 (1 ppm) (ACGIH); IDLH 200 ppm (NIOSH).
Dielectric constant :2.5(-60℃)
Stability :Stable, but pyrophoric - spontaneously flammable in air. Note the very wide explosion limits. Incompatible with oxidizing agents, halogens, nitric acid.
CAS DataBase Reference :7803-51-2(CAS DataBase Reference)
NIST Chemistry Reference :Phosphine(7803-51-2)
EPA Substance Registry System :Phosphine (7803-51-2)
Safety Information
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Description
Phosphine is used primarily in the manufacture of III-IV semiconductor materials by OMCVD and as a dopant in crystalline and amorphous silicon.More related product prices
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