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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Tributylphosphine

Tributylphosphine

Tributylphosphine Structure
  • ₹1742.83 - ₹46565
  • Product name: Tributylphosphine
  • CAS: 998-40-3
  • MF: C12H27P
  • MW: 202.32
  • EINECS:213-651-2
  • MDL Number:MFCD00009462
  • Synonyms:TRI-N-BUTYLPHOSPHINE (10 WT% IN HEXANE);TRIBUTYL PHOSPHINE (TBP);Tri-n-butylphosphine,99%;Tri-n-butylphosphine,99%(10wt%inhexane);Tri-n-butylphosphine,min.93%;cytop 340;tributylphosphine solution;TRI-N-BUTYLPHOSPHINE OR PHOSPHINE, TRIBUTYL
7 prices
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Brand

  • Sigma-Aldrich(India)
  • ALFA India
  • ottokemi

Package

  • 25gm
  • 50g
  • 100gm
  • 100G
  • 250g
  • 2x500g
  • 10VIALS
  • ManufacturerSigma-Aldrich(India)
  • Product number247049
  • Product descriptionTributylphosphine mixture of isomers, 97%
  • Packaging100G
  • Price₹1742.83
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product numberT7567
  • Product descriptionTributylphosphine solution 200?mM (in N-methyl-2-pyrrolidinone), liquid
  • Packaging10VIALS
  • Price₹10400.6
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-014114-95
  • Product descriptionTri-n-butylphosphine, 94%
  • Packaging2x500g
  • Price₹46565
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-014114-30
  • Product descriptionTri-n-butylphosphine, 94%
  • Packaging250g
  • Price₹33199
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-014114-18
  • Product descriptionTri-n-butylphosphine, 94%
  • Packaging50g
  • Price₹6665
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number T 0012
  • Product descriptionTributylphosphine 97%
  • Packaging25gm
  • Price₹4302
  • Updated2022-05-26
  • Buy
  • Manufacturerottokemi
  • Product number T 0012
  • Product descriptionTributylphosphine 97%
  • Packaging100gm
  • Price₹15309
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 247049 Tributylphosphine mixture of isomers, 97% 100G ₹1742.83 2022-06-14 Buy
Sigma-Aldrich(India) T7567 Tributylphosphine solution 200?mM (in N-methyl-2-pyrrolidinone), liquid 10VIALS ₹10400.6 2022-06-14 Buy
ALFA India ALF-014114-95 Tri-n-butylphosphine, 94% 2x500g ₹46565 2022-05-26 Buy
ALFA India ALF-014114-30 Tri-n-butylphosphine, 94% 250g ₹33199 2022-05-26 Buy
ALFA India ALF-014114-18 Tri-n-butylphosphine, 94% 50g ₹6665 2022-05-26 Buy
ottokemi T 0012 Tributylphosphine 97% 25gm ₹4302 2022-05-26 Buy
ottokemi T 0012 Tributylphosphine 97% 100gm ₹15309 2022-05-26 Buy

Properties

Melting point :-65 °C
Boiling point :150 °C50 mm Hg(lit.)
Density :0.81 g/mL at 25 °C(lit.)
vapor density :9 (vs air)
vapor pressure :1.9Pa at 20℃
refractive index :n20/D 1.462(lit.)
Flash point :99 °F
storage temp. :2-8°C
form :liquid
color :Clear colorless to pale yellow
Specific Gravity :0.820 (20/4℃)
Water Solubility :insoluble
Sensitive :Moisture Sensitive/Air Sensitive
BRN :1738261
Stability :Stable, but pyrophoric - spontaneously inflammable in air. Incompatible with oxidizing agents. Moisture sensitive.
InChIKey :TUQOTMZNTHZOKS-UHFFFAOYSA-N
CAS DataBase Reference :998-40-3(CAS DataBase Reference)
NIST Chemistry Reference :Phosphine, tributyl-(998-40-3)
EPA Substance Registry System :Phosphine, tributyl- (998-40-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H251 Self-heating; may catch fire Self-heating substances and mixtures Category 1 Danger GHS hazard pictograms
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P235 Keep cool.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tri-n-butylphosphine is used as a catalyst modifier in the cobalt-catalyzed hydroformylation of alkenes for industrial use. It is also used as a strong reducing agent and polymerization cross-linking catalyst. It is a used as an intermediate for phase transfer catalysts. Used with platinum (II) or (IV) in an intermolecular hydroamination of inactivated alkenes. It is used as 1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.

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