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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Tri-tert-butylphosphine

Tri-tert-butylphosphine

Tri-tert-butylphosphine Structure
  • ₹8117 - ₹40545
  • Product name: Tri-tert-butylphosphine
  • CAS: 13716-12-6
  • MF: C12H27P
  • MW: 202.32
  • EINECS:237-266-4
  • MDL Number:MFCD00015006
  • Synonyms:Phosphine, tris(1,1-dimethylethyl)-;TRI-TERT-BUTYL-PHOSPHANE;TRI-TERT-BUTYLPHOSPHINE;tris(1,1-dimethylethyl)phosphine ;TRI-TERT-BUTYLPHOSPHINE, 1M IN TOLUENE;TRI-TERT-BUTYLPHOSPHINE, TECH., 90%;TERT-BUTYLPHOSPHINE, ELEC. GR., 99.9995%;Tri-t-butylphosphine,99%
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Brand

  • ALFA India

Package

  • 1g
  • 5g
  • ManufacturerALFA India
  • Product numberALF-010178-06
  • Product descriptionTri-tert-butylphosphine, 98%
  • Packaging5g
  • Price₹40545
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-010178-03
  • Product descriptionTri-tert-butylphosphine, 98%
  • Packaging1g
  • Price₹8117
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-010178-06 Tri-tert-butylphosphine, 98% 5g ₹40545 2022-05-26 Buy
ALFA India ALF-010178-03 Tri-tert-butylphosphine, 98% 1g ₹8117 2022-05-26 Buy

Properties

Melting point :30-35 °C(lit.)
Boiling point :102-103 °C13 mm Hg(lit.)
Density :0.861 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
form :solid
Specific Gravity :0.68
Water Solubility :insoluble
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN :1738613
InChIKey :BWHDROKFUHTORW-UHFFFAOYSA-N
CAS DataBase Reference :13716-12-6(CAS DataBase Reference)
NIST Chemistry Reference :Tri-tert-butylphosphine(13716-12-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

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