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ChemicalBook > Product Catalogue >Organic Chemistry >Phosphines >Tri-tert-butylphosphine tetrafluoroborate

Tri-tert-butylphosphine tetrafluoroborate

Tri-tert-butylphosphine tetrafluoroborate Structure
  • ₹4700 - ₹178753.23
  • Product name: Tri-tert-butylphosphine tetrafluoroborate
  • CAS: 131274-22-1
  • MF: C12H28P.BF4
  • MW: 290.13
  • EINECS:672-603-2
  • MDL Number:MFCD04039975
  • Synonyms:Tri-t-butylphosphoniumtetrafluoroborate,99%;fluoroboric acid tri-tert-butylphosphine adduct;tri-tert-butylphosphine fluoroboric acid adduct;Tri-tert-butylphosphonium tetrafluoroborate, 97+%;Tri-tert-butylphosphonium tetrafluoroborate,99%;Tri-tert-butylphosphoniuM tetrafluoroborate, 97+% 1GR;Tri-tert-butylphosphine tetrafluoborate;Tri-tert-butylphosphoniuM tetr
7 prices
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Brand

  • ALFA India
  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 1g
  • 5g
  • 100G
  • ManufacturerALFA India
  • Product numberALF-L19752-03
  • Product descriptionTri-tert-butylphosphonium tetrafluoroborate, 97%
  • Packaging1g
  • Price₹4700
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L19752-06
  • Product descriptionTri-tert-butylphosphonium tetrafluoroborate, 97%
  • Packaging5g
  • Price₹22641
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT2584
  • Product descriptionTri-tert-butylphosphonium Tetrafluoroborate
  • Packaging1G
  • Price₹4700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberT2584
  • Product descriptionTri-tert-butylphosphonium Tetrafluoroborate
  • Packaging5G
  • Price₹15000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number578940
  • Product descriptionTri-tert-butylphosphonium tetrafluoroborate 97%
  • Packaging1G
  • Price₹13877.65
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number578940
  • Product descriptionTri-tert-butylphosphonium tetrafluoroborate 97%
  • Packaging5G
  • Price₹15847.8
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number578940
  • Product descriptionTri-tert-butylphosphonium tetrafluoroborate 97%
  • Packaging100G
  • Price₹178753.23
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
ALFA India ALF-L19752-03 Tri-tert-butylphosphonium tetrafluoroborate, 97% 1g ₹4700 2022-05-26 Buy
ALFA India ALF-L19752-06 Tri-tert-butylphosphonium tetrafluoroborate, 97% 5g ₹22641 2022-05-26 Buy
TCI Chemicals (India) T2584 Tri-tert-butylphosphonium Tetrafluoroborate 1G ₹4700 2022-05-26 Buy
TCI Chemicals (India) T2584 Tri-tert-butylphosphonium Tetrafluoroborate 5G ₹15000 2022-05-26 Buy
Sigma-Aldrich(India) 578940 Tri-tert-butylphosphonium tetrafluoroborate 97% 1G ₹13877.65 2022-06-14 Buy
Sigma-Aldrich(India) 578940 Tri-tert-butylphosphonium tetrafluoroborate 97% 5G ₹15847.8 2022-06-14 Buy
Sigma-Aldrich(India) 578940 Tri-tert-butylphosphonium tetrafluoroborate 97% 100G ₹178753.23 2022-06-14 Buy

Properties

Melting point :261 °C(lit.)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form :Crystals and Chunks
color :White
Water Solubility :Soluble in methylene chloride and chloroform. Slightly soluble in terahydro furan. Insoluble in hexane, toluene and water.
Sensitive :Hygroscopic
BRN :8813613
InChI :InChI=1S/C12H28P.BF4/c1-10(2,3)13(11(4,5)6)12(7,8)9;2-1(3,4)5/h13H,1-9H3;/q2*-1
InChIKey :YSTLBJVHZMEEAC-UHFFFAOYSA-N
SMILES :[P-](C(C)(C)C)(C(C)(C)C)C(C)(C)C.[B-](F)(F)(F)F
CAS DataBase Reference :131274-22-1(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Tri-tert-butylphosphonium tetrafluoroborate is a ligand used in the palladium-catalyzed enantioselective alfa-arylation of N-boc-pyrrolidine. It is also used with a palladium(0)-15-membered, triolefinic, macrocyle in Suzuki cross-coupling reactions of aryl bromides and chlorides. Further, it is used in the Heck coupling of vinyl tosylates with olefins.

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