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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >Diphenylphosphoryl azide

Diphenylphosphoryl azide

Diphenylphosphoryl azide Structure
  • ₹1288.18 - ₹49590
  • Product name: Diphenylphosphoryl azide
  • CAS: 26386-88-9
  • MF: C12H10N3O3P
  • MW: 275.2
  • EINECS:247-644-0
  • MDL Number:MFCD00001987
  • Synonyms:(PHO)2PO-N3;PHOSPHORIC ACID DIPHENYL ESTER AZIDE;PS-DPPA;Diphenylphosphonicazide,97%;DPPA polymer-bound, PS-DPPA;DPPA, Phosphoric acid diphenyl ester azide;DIPHENYLPHOSPHORYL AZIDE;DIPHENYLPHOSPHORYL AZIDE, POLYMER-BOUND
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Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 5G
  • 25G
  • 100G
  • 250G
  • 500G
  • ManufacturerTCI Chemicals (India)
  • Product numberD1672
  • Product descriptionDiphenylphosphoryl Azide min. 97.0 %
  • Packaging5G
  • Price₹2200
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD1672
  • Product descriptionDiphenylphosphoryl Azide min. 97.0 %
  • Packaging25G
  • Price₹5300
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD1672
  • Product descriptionDiphenylphosphoryl Azide min. 97.0 %
  • Packaging250G
  • Price₹24600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number178756
  • Product descriptionDiphenyl phosphoryl azide 97%
  • Packaging5G
  • Price₹1288.18
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number178756
  • Product descriptionDiphenyl phosphoryl azide 97%
  • Packaging25G
  • Price₹5737.25
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number178756
  • Product descriptionDiphenyl phosphoryl azide 97%
  • Packaging100G
  • Price₹20535.03
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number178756
  • Product descriptionDiphenyl phosphoryl azide 97%
  • Packaging500G
  • Price₹49590
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D1672 Diphenylphosphoryl Azide min. 97.0 % 5G ₹2200 2022-05-26 Buy
TCI Chemicals (India) D1672 Diphenylphosphoryl Azide min. 97.0 % 25G ₹5300 2022-05-26 Buy
TCI Chemicals (India) D1672 Diphenylphosphoryl Azide min. 97.0 % 250G ₹24600 2022-05-26 Buy
Sigma-Aldrich(India) 178756 Diphenyl phosphoryl azide 97% 5G ₹1288.18 2022-06-14 Buy
Sigma-Aldrich(India) 178756 Diphenyl phosphoryl azide 97% 25G ₹5737.25 2022-06-14 Buy
Sigma-Aldrich(India) 178756 Diphenyl phosphoryl azide 97% 100G ₹20535.03 2022-06-14 Buy
Sigma-Aldrich(India) 178756 Diphenyl phosphoryl azide 97% 500G ₹49590 2022-06-14 Buy

Properties

Boiling point :157 °C/0.17 mmHg (lit.)
Density :1.277 g/mL at 25 °C (lit.)
refractive index :n20/D 1.551(lit.)
Flash point :>230 °F
storage temp. :2-8°C
solubility :Acetonitrile (Slightly), Chloroform (Slightly), Ethyl Acetate (Sparingly)
form :Liquid
Specific Gravity :1.277
color :slightly yellow
Water Solubility :insoluble
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
BRN :2058967
Stability :Stable. Incompatible with acids, strong oxidizing agents.
InChIKey :SORGEQQSQGNZFI-UHFFFAOYSA-N
CAS DataBase Reference :26386-88-9(CAS DataBase Reference)
NIST Chemistry Reference :Diphenylphosphoryl azide(26386-88-9)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Diphenylphosphonic azide acts as a reagent for the synthesis of peptides and phosphoramidates by reacting with amines. It is also used in the preparation of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtis rearrangement. It is involved in pseudohalogen replacement of the azido group by treatment with nucleophilic reagents, such as water, butanol, ammonia, and various amines. Further, it is used as a hydroazidation catalyst for preparation of organoazides.

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