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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Olefin (cyclic and acyclic) >3,4-Dimethoxy-3-cyclobutene-1,2-dione

3,4-Dimethoxy-3-cyclobutene-1,2-dione

3,4-Dimethoxy-3-cyclobutene-1,2-dione Structure
  • ₹3189 - ₹24800
  • Product name: 3,4-Dimethoxy-3-cyclobutene-1,2-dione
  • CAS: 5222-73-1
  • MF: C6H6O4
  • MW: 142.11
  • EINECS:627-380-6
  • MDL Number:MFCD00101316
  • Synonyms:3-Cyclobutene-1,2-dione,3,4-dimethoxy-;3,4-Dimethoxycyclobut-3-ene-1,2-dione 98%;Dimethyl squarate, 1,2-Dimethoxy-3,4-dioxocyclobut-1-ene;Dimethyl squarate 3,4-Dimethoxy-3-cyclobutene-1,2-dione;SQUARIC ACID DIMETHYL ESTER;3,4-DIMETHOXY-3-CYCLOBUTENE-1,2-DIONE;Squaric acid dimethyl ester,(Dimethyl squarate, 3,4-Dimethoxy-3-cyclobutene-1,2-dione);3,4-DIMETHOXYCYCLOBUTANE-1,2-DIONE
6 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 1G
  • 5G
  • 25G
  • ManufacturerTCI Chemicals (India)
  • Product numberD2099
  • Product description3,4-Dimethoxy-3-cyclobutene-1,2-dione min. 98.0 %
  • Packaging5G
  • Price₹9100
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2099
  • Product description3,4-Dimethoxy-3-cyclobutene-1,2-dione min. 98.0 %
  • Packaging25G
  • Price₹24800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number377406
  • Product description3,4-Dimethoxy-3-cyclobutene-1,2-dione 99%
  • Packaging1G
  • Price₹3409.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number377406
  • Product description3,4-Dimethoxy-3-cyclobutene-1,2-dione 99%
  • Packaging5G
  • Price₹13087.43
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A18186-06
  • Product description3,4-Dimethoxy-3-cyclobutene-1,2-dione, 98%
  • Packaging5g
  • Price₹10386
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A18186-03
  • Product description3,4-Dimethoxy-3-cyclobutene-1,2-dione, 98%
  • Packaging1g
  • Price₹3189
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D2099 3,4-Dimethoxy-3-cyclobutene-1,2-dione min. 98.0 % 5G ₹9100 2022-05-26 Buy
TCI Chemicals (India) D2099 3,4-Dimethoxy-3-cyclobutene-1,2-dione min. 98.0 % 25G ₹24800 2022-05-26 Buy
Sigma-Aldrich(India) 377406 3,4-Dimethoxy-3-cyclobutene-1,2-dione 99% 1G ₹3409.88 2022-06-14 Buy
Sigma-Aldrich(India) 377406 3,4-Dimethoxy-3-cyclobutene-1,2-dione 99% 5G ₹13087.43 2022-06-14 Buy
ALFA India ALF-A18186-06 3,4-Dimethoxy-3-cyclobutene-1,2-dione, 98% 5g ₹10386 2022-05-26 Buy
ALFA India ALF-A18186-03 3,4-Dimethoxy-3-cyclobutene-1,2-dione, 98% 1g ₹3189 2022-05-26 Buy

Properties

Melting point :55-57 °C (lit.)
Boiling point :219.65°C (rough estimate)
Density :1.3863 (rough estimate)
refractive index :1.5800 (estimate)
storage temp. :2-8°C
solubility :DMSO, Methanol (Slightly)
form :Solid
color :Off-White to Pale Brown
Water Solubility :Very soluble in water.
InChIKey :SZBNZTGCAMLMJY-UHFFFAOYSA-N
CAS DataBase Reference :5222-73-1(CAS DataBase Reference)
NIST Chemistry Reference :3,4-Dimethoxy-3-cyclobutene-1,2-dione(5222-73-1)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger GHS hazard pictograms P261, P285, P304+P341, P342+P311,P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P342+P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

Description

3,4-Dimethoxy-3-cyclobutene-1,2-dione (Dimethyl squarate) finds it uses in the synthesis of chiral squaramides, highly enantioselective catalyst for the Friedel-Crafts reactions of indoles, 3-(hydroxyamino)-4-methoxy-3-cyclobutene-1,2-dione, squarate derivatives of the O-SP-core antigens, methyl squarate derivative of the Ogawa O-SP-core antigen, o-quinodimethanes, benzocyclobutenes, quinones. It is employed as a starting material in the preparation of o-quinodimethanes, benzocyclobutenes, and quinones.

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