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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphorus halide >(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide

(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Structure
  • ₹2900 - ₹99674
  • Product name: (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide
  • CAS: 52509-14-5
  • MF: C22H22BrO2P
  • MW: 429.29
  • EINECS:257-977-3
  • MDL Number:MFCD00011966
  • Synonyms:LABOTEST-BB LT00233112;(1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;(1,3-DIOXOLANE-2-YL METHYL) TRIPHENYL PHOSPHONIUM BROMIDE;TRIPHENYL-1,3-DIOXOLAN-2-YLMETHYL-PHOSPHONIUM BROMIDE;2-(1,3)-DIOXOLANE-2-YL-METHYLTRIPHENYLPHOSPHONIUM BROMIDE;(1,3-DIOXOLAN-2-YLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE 98%;(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98 %;Phosphonium, (1,3-dioxolan-2-ylmethyl)triphenyl-, bromide
6 prices
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Brand

  • TCI Chemicals (India)
  • ALFA India
  • Sigma-Aldrich(India)

Package

  • 5G
  • 10g
  • 25G
  • 50g
  • 250g
  • ManufacturerTCI Chemicals (India)
  • Product numberD2164
  • Product description(1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide
  • Packaging5G
  • Price₹2900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberD2164
  • Product description(1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide
  • Packaging25G
  • Price₹11300
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A18882-30
  • Product description(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%
  • Packaging250g
  • Price₹99674
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A18882-18
  • Product description(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%
  • Packaging50g
  • Price₹19004
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number223859
  • Product description(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide 98%
  • Packaging5G
  • Price₹9038.88
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-A18882-09
  • Product description(1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98%
  • Packaging10g
  • Price₹5317
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) D2164 (1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide 5G ₹2900 2022-05-26 Buy
TCI Chemicals (India) D2164 (1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide 25G ₹11300 2022-05-26 Buy
ALFA India ALF-A18882-30 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98% 250g ₹99674 2022-05-26 Buy
ALFA India ALF-A18882-18 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98% 50g ₹19004 2022-05-26 Buy
Sigma-Aldrich(India) 223859 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide 98% 5G ₹9038.88 2022-06-14 Buy
ALFA India ALF-A18882-09 (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide, 98% 10g ₹5317 2022-05-26 Buy

Properties

Melting point :193-195 °C(lit.)
storage temp. :Store below +30°C.
solubility :Chloroform (Slightly), Methanol (Slightly)
form :Powder or Crystals
color :White to light brown
Water Solubility :Soluble in water (20°C).
Sensitive :Hygroscopic
InChIKey :FRHRVQQUICVJDG-UHFFFAOYSA-M
CAS DataBase Reference :52509-14-5(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

It finds its applications as a reagent for Wittig olefinations with introduction of a 1,3-dioxolane moiety. It is applied as a reactant for the preparation of a ratiometric fluorescent probe for specific detection of cysteine over homocysteine and glutathione, for microwave-assisted synthesis of KN-93 as inhibitor of calmodulin kinase II, for the preparation of fluorinated spirobenzofuran piperidines as s1 receptor ligands, in the synthesis and antitumor agents, in regio-selective preparation of indole derivatives via rhodium-catalyzed domino hydroformylation/indolization.

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