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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphorus halide >(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide

(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide Structure
  • ₹3029 - ₹13899.3
  • Product name: (tert-Butoxycarbonylmethyl)triphenylphosphanium bromide
  • CAS: 59159-39-6
  • MF: C24H26BrO2P
  • MW: 457.34
  • EINECS:
  • MDL Number:MFCD00075527
  • Synonyms:tert-Butoxycarbonylmethyltriphenylphosphoniumbrom;(tert-Butoxycarbonylmethyl)tripheenyphosphonium bromide;(TERT-BUTOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE;carbo-tert-butoxymethyl triphenylphosphonium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphanium bromide;(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98 %;triphenyl tert butoxycarbonyl Methyl phosphoniuM broMide;T-butoxycarbonylMethyltriphenylphosphoniuMbroMide
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 5g
  • 10G
  • 25G
  • 50G
  • ManufacturerTCI Chemicals (India)
  • Product numberB3928
  • Product description(tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide
  • Packaging25G
  • Price₹8500
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number369047
  • Product description(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide 98%
  • Packaging10G
  • Price₹3842.88
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number369047
  • Product description(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide 98%
  • Packaging50G
  • Price₹13899.3
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L15165-06
  • Product description(tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98%
  • Packaging5g
  • Price₹3029
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B3928 (tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide 25G ₹8500 2022-05-26 Buy
Sigma-Aldrich(India) 369047 (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide 98% 10G ₹3842.88 2022-06-14 Buy
Sigma-Aldrich(India) 369047 (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide 98% 50G ₹13899.3 2022-06-14 Buy
ALFA India ALF-L15165-06 (tert-Butoxycarbonylmethyl)triphenylphosphonium bromide, 98% 5g ₹3029 2022-05-26 Buy

Properties

Melting point :178 °C (dec.)(lit.)
storage temp. :Inert atmosphere,Room Temperature
solubility :soluble in Methanol
form :powder to crystal
color :White to Almost white
BRN :4631405
CAS DataBase Reference :59159-39-6(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Reactant for:
  • Rhodium-catalyzed asymmetric hydrogenation reactions
  • Wittig reaction
  • Wittig methylenation
  • Preparation of N-(phenylmethyl)-cis-pyrrolidinediacetic acid esters via double aza-Michael addition reaction
  • Stereoselective preparation of of α-fluoro-α,β-unsaturated esters via deprotonation, followed by fluorination and stereoselective Wittig olefination with aldehydes
  • Wittig chain extension reactions

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