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ChemicalBook > Product Catalogue >Organic Chemistry >Heterocyclic Compounds >(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Structure
  • ₹1530 - ₹18636.9
  • Product name: (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
  • CAS: 64536-78-3
  • MF: C31H47F6IrNP2
  • MW: 801.88
  • EINECS:
  • MDL Number:MFCD00075097
  • Synonyms:(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTA- DIENE)(PYRIDINE)IRIDIUM(I) PF6;(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,99%;(1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate;(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate,99%CRABTREE'SCATALYST;1,5-Cyclooctadiene-(pyridyl)-(tricyclohexylphosphine)-iridium hexafluoropho;(cycloocta-1,5-diene)pyridyl(tricyclohexyl-phosphine)iridium(I)hexafluorophosphate Crabtree's catalyst;
    (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluoro phosphate;Hexafluorophosphate (tricyclohexyl phosphine) (1,5-cyclooctadiene) (pyridine) iridium
Price5 Properties Safety Information Description
5 prices
Selected condition：

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 50MG
  • 100MG
  • 250MG
  • ManufacturerTCI Chemicals (India)
  • Product numberC2824
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate
  • Packaging100MG
  • Price₹8000
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number29590
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate ≥99.0% (C)
  • Packaging250MG
  • Price₹18636.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number337498
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate 85%
  • Packaging250MG
  • Price₹5940
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number337498
  • Product description(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate 85%
  • Packaging50MG
  • Price₹1530
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-042057-MD
  • Product description1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
  • Packaging250mg
  • Price₹7610
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) C2824 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate 100MG ₹8000 2022-05-26 Buy
Sigma-Aldrich(India) 29590 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate ≥99.0% (C) 250MG ₹18636.9 2022-06-14 Buy
Sigma-Aldrich(India) 337498 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate 85% 250MG ₹5940 2022-06-14 Buy
Sigma-Aldrich(India) 337498 (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate 85% 50MG ₹1530 2022-06-14 Buy
ALFA India ALF-042057-MD 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99% 250mg ₹7610 2022-05-26 Buy

Properties

Melting point :175 °C (dec.)(lit.)
Density :1.67 g/cm3
storage temp. :Inert atmosphere,Room Temperature
solubility :Chloroform (Slightly)
form :Crystalline Powder
color :Orange
Water Solubility :Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
Sensitive :Moisture Sensitive
Merck :13,2594

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

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Suppliers and manufacturers

Johnson Matthey Chemicals India Pvt Ltd A.J Chemicals Grr Fine Chem/Grr Exports Clearsynth Labs Souvenier Chemicals Johnson Matthey Chemicals India Pvt., Ltd. CHEMSWORTH Alfa Aesar TCI Chemicals (India) Pvt. Ltd.
ATK CHEMICAL COMPANY LIMITED