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(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Structure
  • ₹5328 - ₹431978.7
  • Product name: (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
  • CAS: 301224-40-8
  • MF: C31H37Cl2N2ORu
  • MW: 625.62
  • EINECS:608-446-3
  • MDL Number:MFCD03701614
  • Synonyms:(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM;RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE];[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium;Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium;(1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM;(1,3-DiMesityliMidazolidin-2-ylidene)(2-isopropoxybenzylidene)rutheniuM(VI) chloride;Dichloro(1,3-diMesityl-2-iMidazolidinylidene)(2-isopropoxybenzylidene)rutheniuM;Hoveyda-Grubbs Catalyst 2nd Generation,97%
Price5 Properties Safety Information Description
5 prices
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Brand

  • Sigma-Aldrich(India)

Package

  • 100MG
  • 500MG
  • 2G
  • 10G
  • 25G
  • ManufacturerSigma-Aldrich(India)
  • Product number569755
  • Product descriptionHoveyda-Grubbs Catalyst® M720 Umicore, 97%
  • Packaging100MG
  • Price₹5328
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number569755
  • Product descriptionHoveyda-Grubbs Catalyst® M720 Umicore, 97%
  • Packaging500MG
  • Price₹26606.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number569755
  • Product descriptionHoveyda-Grubbs Catalyst® M720 Umicore, 97%
  • Packaging2G
  • Price₹62148.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number569755
  • Product descriptionHoveyda-Grubbs Catalyst® M720 Umicore, 97%
  • Packaging10G
  • Price₹215706.3
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number569755
  • Product descriptionHoveyda-Grubbs Catalyst® M720 Umicore, 97%
  • Packaging25G
  • Price₹431978.7
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 100MG ₹5328 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 500MG ₹26606.7 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 2G ₹62148.9 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 10G ₹215706.3 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 25G ₹431978.7 2022-06-14 Buy

Properties

Melting point :216-220 °C(lit.)
storage temp. :2-8°C
solubility :Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form :Solid
color :Green to Very Dark Green
Stability :Hygroscopic
InChIKey :ZRPFJAPZDXQHSM-UHFFFAOYSA-L
CAS DataBase Reference :301224-40-8
EPA Substance Registry System :Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-.kappa.O)phenyl]methylene-.kappa.C]-, (SP-5-41)- (301224-40-8)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.

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Suppliers and manufacturers

career henan chemical co
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
₹1.00 /1KG
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM CAS:301224-40-8
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