(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
![(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Structure](CAS/GIF/301224-40-8.gif)
- CAS No.
- 301224-40-8
- Chemical Name:
- (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
- Synonyms
- HOVEYDA-GRUBBS;HOVEYDA-GRUBBS CATALYST;Hoveyda-Grubbs Catalyst 2nd;Hoveyda-Grubbs 2nd;Hoveyda-Grubbs Catalyst 2nd Generation;[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium;NH22260;eneration;Hoveyda-g;yst 2nd g
- CBNumber:
- CB0667713
- Molecular Formula:
- C31H37Cl2N2ORu
- Molecular Weight:
- 625.62
- MOL File:
- 301224-40-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/4/23 13:52:06
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Properties
Melting point | 216-220 °C(lit.) |
---|---|
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly) |
form | Solid |
color | Green to Very Dark Green |
Stability | Hygroscopic |
InChIKey | ZRPFJAPZDXQHSM-UHFFFAOYSA-L |
CAS DataBase Reference | 301224-40-8 |
EPA Substance Registry System | Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-.kappa.O)phenyl]methylene-.kappa.C]-, (SP-5-41)- (301224-40-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS05 |
---|---|
Signal word | Danger |
Hazard statements | H314-H227 |
Precautionary statements | P501-P210-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405 |
WGK Germany | 3 |
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM price More Price(5)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 569755 | Hoveyda-Grubbs Catalyst® M720 Umicore, 97% | 301224-40-8 | 100MG | ₹5328 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 569755 | Hoveyda-Grubbs Catalyst® M720 Umicore, 97% | 301224-40-8 | 500MG | ₹26606.7 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 569755 | Hoveyda-Grubbs Catalyst® M720 Umicore, 97% | 301224-40-8 | 2G | ₹62148.9 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 569755 | Hoveyda-Grubbs Catalyst® M720 Umicore, 97% | 301224-40-8 | 10G | ₹215706.3 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 569755 | Hoveyda-Grubbs Catalyst® M720 Umicore, 97% | 301224-40-8 | 25G | ₹431978.7 | 2022-06-14 | Buy |
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Chemical Properties,Uses,Production
Chemical Properties
Bright green crystalline powder
Uses
It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 170)Suppliers
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 32760 | 60 | Inquiry |
career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29896 | 58 | Inquiry |
Accela ChemBio Inc. | +1-858-6993322 | United States | 19309 | 58 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49391 | 58 | Inquiry |
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | CHINA | 21149 | 58 | Inquiry |
WinWin Chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | China | 14278 | 58 | Inquiry |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | China | 23556 | 58 | Inquiry |
301224-40-8((1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM)Related Search:
1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE
Dicyclopentadiene
Bis(triphenylphosphine)palladium(II) chloride
Tetrakis(triphenylphosphine)palladium
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
Ruthenium(III) chloride hydrate
(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II)
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II)
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
GRUBBS CATALYST 2ND GENERATION
Ruthenium
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride
RUTHENIUM, [1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-[[2-ISOPROPOXY-5-(N-RESIN-LINKED AMINOSULFONYL)PHENYL]METHYLENE]
chevron_left
1of4
chevron_right
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE]
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium
Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium
(1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM
(1,3-DiMesityliMidazolidin-2-ylidene)(2-isopropoxybenzylidene)rutheniuM(VI) chloride
Dichloro(1,3-diMesityl-2-iMidazolidinylidene)(2-isopropoxybenzylidene)rutheniuM
Hoveyda-Grubbs Catalyst 2nd Generation,97%
Hoveyda-Grubbs Catalyst 2nd Generation 97%
NH22260
eneration
Hoveyda-g
rubbs CataL
yst 2nd g
Hoveyda-Grubbs Catalyst(TM) 2nd Generation
Hoveyda-Grubbs CataL
yst 2nd Generation
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM ISO 9001:2015 REACH
HOVEYDA-GRUBBS CATALYST
Hoveyda-Grubbs Catalyst 2nd Generation
Hoveyda-Grubbs Catalyst 2nd
Hoveyda-Grubbs 2nd
HOVEYDA-GRUBBS
[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
Hoveyda-Grubbs G2
[1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II)
Hoveyda-Grubbs Catalyst 3nd Generation
Dichloro(1,3-Dimesityl-2-imidazolidinylidene)(o-isopropoxyphenylmethylene)ruthenium
Hoveyda-Grubbs II
301224-40-8
C31H38Cl2N2ORu
Catalysis and Inorganic Chemistry
Metathesis Catalysts
Ru