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(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Structure
CAS No.
301224-40-8
Chemical Name:
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
Synonyms
HOVEYDA-GRUBBS;HOVEYDA-GRUBBS CATALYST;Hoveyda-Grubbs Catalyst 2nd;Hoveyda-Grubbs 2nd;Hoveyda-Grubbs Catalyst 2nd Generation;[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium;NH22260;eneration;Hoveyda-g;yst 2nd g
CBNumber:
CB0667713
Molecular Formula:
C31H37Cl2N2ORu
Molecular Weight:
625.62
MOL File:
301224-40-8.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02
Request For Quotation

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Properties

Melting point 216-220 °C(lit.)
storage temp. 2-8°C
solubility Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form Solid
color Green to Very Dark Green
Stability Hygroscopic
InChIKey ZRPFJAPZDXQHSM-UHFFFAOYSA-L
CAS DataBase Reference 301224-40-8
EPA Substance Registry System Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-.kappa.O)phenyl]methylene-.kappa.C]-, (SP-5-41)- (301224-40-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314-H227
Precautionary statements  P501-P210-P264-P280-P370+P378-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405
WGK Germany  3

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 301224-40-8 100MG ₹5328 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 301224-40-8 500MG ₹26606.7 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 301224-40-8 2G ₹62148.9 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 301224-40-8 10G ₹215706.3 2022-06-14 Buy
Sigma-Aldrich(India) 569755 Hoveyda-Grubbs Catalyst® M720 Umicore, 97% 301224-40-8 25G ₹431978.7 2022-06-14 Buy
Product number Packaging Price Buy
569755 100MG ₹5328 Buy
569755 500MG ₹26606.7 Buy
569755 2G ₹62148.9 Buy
569755 10G ₹215706.3 Buy
569755 25G ₹431978.7 Buy

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Chemical Properties,Uses,Production

Chemical Properties

Bright green crystalline powder

Uses

It′s a phosphine free version of Grubbs 2nd Generation Catalyst with comparable reactivity, but initiates more readily at lower temperatures. Efficient for metathesis of electron-deficient substrates including fluorinated olefins. Demonstrated in multiple large-scale pharmaceutical applications.
It can be used as a catalyst for olefin cross-metathesis with fluorinated olefins (CM), ring-closing metathesis (RCM), ring-opening metathesis (ROM), and a sequence of a metathesis reaction and subsequent dihydroxylation of the newly formed double bond.

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Preparation Products And Raw materials

Raw materials

1,2-Bis(diphenylphosphino)ethane Benzene, 1-ethenyl-2-(1-Methylethoxy)- Grubbs catalyst 2nd generation

Preparation Products

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Suppliers

Global( 178)Suppliers
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A.J Chemicals 91-9810153283 New Delhi, India 6100 58 Inquiry
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Capot Chemical Co.,Ltd. +86-（0）57185586718 +86-13336195806 China 29730 60 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 33024 60 Inquiry
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CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49732 58 Inquiry
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd +8613580539051 CHINA 21142 58 Inquiry
Win-Win chemical CO., Limited +86-0086-577-64498589 +86-15355981851 China 14442 58 Inquiry
ANHUI WITOP BIOTECH CO., LTD +8615255079626 China 23541 58 Inquiry
Supplier Advantage
A.J Chemicals 58
XINXIANG RUNYU MATERIAL CO., LTD. 58
Capot Chemical Co.,Ltd. 60
ATK CHEMICAL COMPANY LIMITED 60
career henan chemical co 58
Accela ChemBio Inc. 58
CONIER CHEM AND PHARMA LIMITED 58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd 58
Win-Win chemical CO., Limited 58
ANHUI WITOP BIOTECH CO., LTD 58

301224-40-8((1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM)Related Search:

1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE Dicyclopentadiene Bis(triphenylphosphine)palladium(II) chloride Tetrakis(triphenylphosphine)palladium [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Ruthenium(III) chloride hydrate (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II)
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II) DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II) Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium GRUBBS CATALYST 2ND GENERATION Ruthenium
(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride RUTHENIUM, [1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-[[2-ISOPROPOXY-5-(N-RESIN-LINKED AMINOSULFONYL)PHENYL]METHYLENE]
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(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE] [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium (1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM (1,3-DiMesityliMidazolidin-2-ylidene)(2-isopropoxybenzylidene)rutheniuM(VI) chloride Dichloro(1,3-diMesityl-2-iMidazolidinylidene)(2-isopropoxybenzylidene)rutheniuM Hoveyda-Grubbs Catalyst 2nd Generation,97% Hoveyda-Grubbs Catalyst 2nd Generation 97% NH22260 eneration Hoveyda-g rubbs CataL yst 2nd g Hoveyda-Grubbs Catalyst(TM) 2nd Generation Hoveyda-Grubbs CataL yst 2nd Generation (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM ISO 9001：2015 REACH HOVEYDA-GRUBBS CATALYST Hoveyda-Grubbs Catalyst 2nd Generation Hoveyda-Grubbs Catalyst 2nd Hoveyda-Grubbs 2nd HOVEYDA-GRUBBS [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium Hoveyda-Grubbs G2 [1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II) Hoveyda-Grubbs Catalyst 3nd Generation Dichloro(1,3-Dimesityl-2-imidazolidinylidene)(o-isopropoxyphenylmethylene)ruthenium Hoveyda-Grubbs II Hoveyda-Grubbs Catalyst? M720 Hoveyda-Grubbs Catalyst?M720 301224-40-8 C31H38Cl2N2ORu Catalysis and Inorganic Chemistry Metathesis Catalysts Ru