ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic palladium >Bis(triphenylphosphine)palladium(II) Dichloride
Bis(triphenylphosphine)palladium(II) Dichloride
- CAS No.
- 13965-03-2
- Chemical Name:
- Bis(triphenylphosphine)palladium(II) Dichloride
- Synonyms
- DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;(PPh3)2PdCl2;DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE;Bis(triphenylphosphine)dichloropalladium;BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);TRIPHENYLPHOSPHINE PALLADIUM CHLORIDE;Bis(triphenylphosphine)palladium(ll) chloride;PALLADIUM BIS(TRIPHENYLPHOSPHINE) DICHLORIDE
- CBNumber:
- CB9364066
- Molecular Formula:
- C36H30Cl2P2Pd
- Molecular Weight:
- 701.9
- MOL File:
- 13965-03-2.mol
- Modify Date:
- 2024/8/15 19:00:21
| Melting point | 260°C |
|---|---|
| vapor pressure | 0Pa at 25℃ |
| RTECS | RT3578000 |
| storage temp. | Store below +30°C. |
| solubility | Chloroform (Slightly), Dichloromethane (Slightly, Heated), Methanol (Slightly, |
| form | Powder |
| color | Yellow |
| Water Solubility | Insoluble in water. Soluble in benzene, and toluene. |
| Sensitive | Hygroscopic |
| BRN | 4935975 |
| InChI | InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2 |
| InChIKey | ILBDOZRDKNIJBS-UHFFFAOYSA-N |
| SMILES | P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl |
| LogP | 5.69 at 20℃ |
| CAS DataBase Reference | 13965-03-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317-H413 | |||||||||
| Precautionary statements | P261-P272-P273-P280-P302+P352-P333+P313 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 36/37/38-22-40-19 | |||||||||
| Safety Statements | 37/39-26-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10-21 | |||||||||
| TSCA | No | |||||||||
| HS Code | 28439090 | |||||||||
| NFPA 704 |
|
Bis(triphenylphosphine)palladium(II) Dichloride price More Price(23)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 8.04174 | Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd) for synthesis | 13965-03-2 | 500MG | ₹6980 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.04174 | Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd) for synthesis | 13965-03-2 | 1G | ₹7610.01 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 8.04174 | Bis(triphenylphosphine)palladium(II) chloride (15.2% Pd) for synthesis | 13965-03-2 | 5G | ₹22350 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 741248 | Bis(triphenylphosphine)palladium(II) dichloride | 13965-03-2 | 1G | ₹2808.3 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 412740 | Bis(triphenylphosphine)palladium(II) dichloride | 13965-03-2 | 250MG | ₹1520.7 | 2022-06-14 | Buy |
Bis(triphenylphosphine)palladium(II) Dichloride Chemical Properties,Uses,Production
Chemical Properties
Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.
Uses
Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.
Synthesis
The synthesis of Bis(triphenylphosphine)palladium(II) chloride can be achieved by the reaction of palladium(II) chloride with triphenylphosphine, resulting in the formation of Bis(triphenylphosphine)palladium(II) chloride. This chemical process is represented by the balanced equation: PdCl2 + 2 PPh3 → PdCl2(PPh3)2.
General Description
Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.
Bis(triphenylphosphine)palladium(II) Dichloride Preparation Products And Raw materials
Raw materials
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Bis(triphenylphosphine)palladium(II) Dichloride Spectrum
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