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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Phosphine ligand >1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,

1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,  Structure
  • ₹11055.6 - ₹607836
  • Product name: 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
  • CAS: 95408-45-0
  • MF: C26H38Cl2FeP2Pd
  • MW: 645.7
  • EINECS:664-483-5
  • MDL Number:MFCD08064219
  • Synonyms:1,1'-Bis (di-t-butylphosphino);Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladiuM(II), Pd 16.3%;PdCl2(dtbpf), 15% Pd, Product of UMicore;[1,1'-Bis(di-tert-butylphosphino)ferrocene]dichlor;1,1′-Bis-(di-tert.-butylphosphino-)ferrocen-palladiumdichlorid;[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II)Dichloride,98%;1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, ;Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II),99%
6 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • 5G
  • 50G
  • ManufacturerTCI Chemicals (India)
  • Product numberB3160
  • Product description[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride
  • Packaging1G
  • Price₹11900
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB3160
  • Product description[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride
  • Packaging5G
  • Price₹40600
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number701602
  • Product description[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98%
  • Packaging250MG
  • Price₹11055.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number701602
  • Product description[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98%
  • Packaging1G
  • Price₹25019.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number701602
  • Product description[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98%
  • Packaging5G
  • Price₹78110.7
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number701602
  • Product description[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98%
  • Packaging50G
  • Price₹607836
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B3160 [1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride 1G ₹11900 2022-05-26 Buy
TCI Chemicals (India) B3160 [1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride 5G ₹40600 2022-05-26 Buy
Sigma-Aldrich(India) 701602 [1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98% 250MG ₹11055.6 2022-06-14 Buy
Sigma-Aldrich(India) 701602 [1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98% 1G ₹25019.4 2022-06-14 Buy
Sigma-Aldrich(India) 701602 [1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98% 5G ₹78110.7 2022-06-14 Buy
Sigma-Aldrich(India) 701602 [1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II) 98% 50G ₹607836 2022-06-14 Buy

Properties

Melting point :203-208 °C
storage temp. :-20°C
solubility :Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.
form :crystal
color :dark purple
InChI :InChI=1S/2C13H19P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*14H,1-6H3;2*1H;;/q;;;;+2;/p-2
InChIKey :ORDFDLUOXDTTTD-UHFFFAOYSA-L
SMILES :C(P1([Pd+2](P(C(C)(C)C)(C(C)(C)C)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]18C9=3)([Cl-])[Cl-])C(C)(C)C)(C)(C)C
CAS DataBase Reference :95408-45-0

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.

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